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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillan Magazines Ltd.
    Nature 398 (1999), S. 663-664 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The manufacture and emission of chlorofluorocarbons (CFCs), our inadvertent global experiment in modifying the Earth's stratosphere, has damaged the ozone layer for decades to come. The Montreal Protocol, which was agreed in 1987 and revised several times in the 1990s, and has the aim of reducing ...
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 312 (1984), S. 227-231 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] An increase in the concentration of inorganic chlorine to levels comparable to that of oxidized reactive nitrogen could cause a significant change in the chemistry of the lower stratosphere leading to a reduction potentially larger than 15% in the column density of ozone. This could occur, for ...
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 367 (1994), S. 505-508 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] INTERNATIONAL agreements have been enacted to protect the ozone layer by regulating the release of chlorine- and bromine-bearing chemicals such as the chlorofluorocarbons and the halons. One of the criteria by which such chemicals are assessed and regulated is the ozone depletion potential ...
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 355 (1992), S. 534-537 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The reaction HC1 + HOCl[+PSC] ^ C12[+PSC + H20] (1) proceeds rapidly3'4 on both cold water-ice and solid nitric acid trihydrate, but is expected to be slow on sulphuric acid aerosols unless they are dilute or partially neutralized3'30. It probably proceeds through the adsorption of ...
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 281 (1979), S. 185-188 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Oxidation of CS2 and COS initiated by reaction with OH can provide a source of atmospheric SO2 as large as 12 Mtonnes S yr−1 and may represent the dominant source of SO2 in remote regions of the marine ...
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 293 (1981), S. 535-539 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Abundances of primordial noble gases are lower for Mars than for Earth, but are higher for Venus. The data for Venus are attributed to implantation of solar wind in small preplanetary particles. Results for Mars are explained by escape of gas from planetesimals with radius between 5 and 100 km ...
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  • 7
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 317 (1985), S. 221-225 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Estimates of continental sources of CFC-11, CFC-12, CCl4, CH3CCl3 and N2O are derived from the atmospheric lifetime experiment in Adrigole, Ireland, and anthropogenic emissions of CCl4 and N2O from Europe have been identified. ...
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 344 (1990), S. 729-734 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The rise in atmospheric chlorine levels caused by the emission of chlorofluorocarbons and other halocarbons is thought to be the main cause of the appearance of the Antarctic ozone 'hole' in the late 1970s, and the more modest ozone depletion observed over parts of the Northern ...
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 37 (2000), S. 245-282 
    ISSN: 1573-0662
    Keywords: photolysis rates ; tropospheric chemistry ; chemical transport modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Photolysis rates in the troposphere are greatly affected by the presenceof cloud and aerosol layers. Yet, the spatial variability of theselayers along with the difficulty of multiple-scattering calculationsfor large particles makes their inclusion in 3-D chemical transportmodels computationally very expensive.This study presents a flexible and accurate photolysis scheme, Fast-J,which calculates photolysis rates in the presence of an arbitrary mix ofcloud and aerosol layers. The algorithm is sufficiently fast to allow thescheme to be incorporated into 3-D global chemical transport models andhave photolysis rates updated hourly. It enables tropospheric chemistrysimulations to include directly the physical properties of the scatteringand absorbing particles in the column, including the full, untruncatedscattering phase function and the total, uncorrected optical depth.The Fast-J scheme is compared with earlier methods that have been usedin 3-D models to parameterize the effects of clouds on photolysis rates.The impact of Fast-J on tropospheric ozone chemistry is demonstratedwith the UCI tropospheric CTM.
    Type of Medium: Electronic Resource
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  • 10
    Publication Date: 2019-09-09
    Description: Sunlight drives the Earth’s weather, climate, chemistry, and biosphere. Recent efforts to improve solar heating codes in climate models focused on more accurate treatment of the absorption spectrum or fractional clouds. A mostly forgotten assumption in climate models is that of a flat Earth atmosphere. Spherical atmospheres intercept 2.5 W⋅m−2 more sunlight and heat the climate by an additional 1.5 W⋅m−2 globally. Such a systematic shift, being comparable to the radiative forcing change from preindustrial to present, is likely to produce a discernible climate shift that would alter a model’s skill in simulating current climate. Regional heating errors, particularly at high latitudes, are several times larger. Unlike flat atmospheres, constituents in a spherical atmosphere, such as clouds and aerosols, alter the total amount of energy received by the Earth. To calculate the net cooling of aerosols in a spherical framework, one must count the increases in both incident and reflected sunlight, thus reducing the aerosol effect by 10 to 14% relative to using just the increase in reflected. Simple fixes to the current flat Earth climate models can correct much of this oversight, although some inconsistencies will remain.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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