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  • 1
    Electronic Resource
    Electronic Resource
    Bromsulfenyl(trihalogen)phosphonium-Salze Cl3-nBrnPSBr+AsF6- (n = 0 - 3) und Cl3PSBr+SbF6-  -  Oxidative Bromierung von Thiophosphorylhalogeniden (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 615 (1992), S. 114-116 
    Details
    ISSN: 0044-2313
    Keywords: Bromosulfenyl(trihalogeno)phosphonium salts ; preparation ; vibrational spectra ; NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Bromosulfenyl(trihalogeno)phosphonium Salts Cl3-nBrnPSBr+AsF6- (n = 0 - 3) and Cl3PSBr+SbF6-  -  Oxidative Bromination of ThiophosphorylhalidesThe bromosulfenyl(trihalogeno)phosphonium salts Cl3-nBrnPSBr+AsF6- (n = 0 - 3) and Cl3PSBr+SbF6- are prepared by oxidative bromination of the corresponding thiophosphorylhalides with Br2/MF5 (M = As, Sb) and characterized by vibrational and NMR spectroscopy.
    Notes: Die Bromsulfenyl(trihalogen)phosphonium Salze Cl3-nBrnPSBr+AsF6- (n = 0 - 3) und Cl3PSBr+SbF6- werden durch oxidative Bromierung der entsprechenden Thiophosphorylhalogenide mit Br2/MF5 (M = As, Sb) dargestellt und schwingungs- sowie NMR-spektroskopisch untersucht.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926150923
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  • 2
    Electronic Resource
    Electronic Resource
    Die Darstellung der Methylthio(trihalogen)phosphonium-Salze ClnBr3-nPSCH3+MF6-(n = 0-3; M = As, Sb) und Hal3PSCH3+SbCl6-(Hal = Br, Cl) (1991)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 604 (1991), S. 105-112 
    Details
    ISSN: 0044-2313
    Keywords: Methylthio(trihalogeno)phosphonium salts ; preparation ; vibrational spectra ; NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Preparation of Methylthio(trihalogeno)phosphonium Salts ClnBr3-nPSCH3+MF6-(n = 0-3; M = As, Sb) and Hal3PSCH3+SbCl6-(Hal = Br, Cl)The methylthio(trihalogeno) phosphonium salts BrnCl3-nPSCH3+MF6- (n = 0-3; M = As, Sb) are prepared by methylation of the corresponding thiophosphorylhalides BrnCl3-nPS in the system SO2/CH3F/MF5. The hexachloroantimonates Hal3PSCH3+SbCl6-(Hal = Br, Cl) are synthesized by thiomethylation of PBr3 and PCl3 with CH3SCl/SbCl5. All salts are characterized by vibrational and NMR spectroscopy.
    Notes: Die Methylthio(trihalogen)phosphonium-Salze BrnCl3-nPSCH3+MF6-(n = 0-3; M = As, Sb) werden durch Methylierung der Thiophosphorylhalogenide BrnCl3-nPS mit CH3OSO+MF6- in flüssigem SO2 dargestellt. Die Hexachloroantimonate Hal3PSCH3+SbCl6-(Hal = Br, Cl) werden durch Thiomethylierung von PBr3 und PCl3 mit CH3SCl/SbCl5 erhalten. Alle Verbindungen werden durch ihre Schwingungs- und NMR-Spektren charakterisiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19916040114
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  • 3
    Electronic Resource
    Electronic Resource
    Darstellung von N-Methyl-N-chlornitryl-hexafluorometallaten ON(Cl)CH3+MF6- (M = As, Sb) (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1743-1746 
    Details
    ISSN: 0044-2313
    Keywords: N-metyl-N-chloronitryl hexafluoro metallates ; nitryl cation ; vibrational spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of N-Methyl-N-chlornitryl Hexafluoro Metallates ON(Cl)CH3+MF6- (M = As, Sb).The preparation of ON(Cl)CH3+MF6- (M = As, Sb) by methylation of ONCl with CH3OSO+MF6- (M = As, Sb) is reported. Both salts were unlimited stable at - 78°C. The nitryl cation which is isoelectronic with acetyl chloride was identified by vibrational spectroscopy as N-chloro-N-hydroxy-methaneiminium cation in the solid state.
    Notes: Die Darstellung der N-Methyl-N-chlornitryl-hexafluorometallate ON(Cl)CH3+MF6- (M = As, Sb) erfolgt durch Methylierung von ONCl mit CH3OSO+MF6-. Beide Salze sind unterhalb von - 78°C unbegrenzt haltbar. Das mit Acetylchlorid isoelektronische Nitrylkation erfährt im Festkörper nach schwingungsspektroskopischen Untersuchungen eine Tautomerie zu einem N-Chlor-N-hydroxo-methaniminium-Kation.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936191020
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  • 4
    Electronic Resource
    Electronic Resource
    Über die Darstellung der Bis(triphenylsilyl)-sulfane (C6H5)3Si—Sx—Si(C6H5)3 (x = 3, 4) und die Kristallstruktur von (C6H5)3Si—S4—Si(C6H5)3Professor Friedo Huber zum 65. Geburtstage gewidmet (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 981-986 
    Details
    ISSN: 0044-2313
    Keywords: Bis(triphenylsilyl)sulfanes ; preparation ; single crystal X-ray structure ; vibrational spectra ; NMR spectra ; UV-VIS spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Preparation of Bis(triphenylsilyl)sulfanes (C6H5)3Si—Sx—Si(C6H5)3 (x = 3, 4) and the Crystal Structure of (C6H5)3Si—S4—Si(C6H5)3The preparation of the bis(triphenylsilyl)sulfanes Ph3Si—Sx—SiPh3 (x = 3, 4) from Ph3SiSNa and SCl2 resp. S2Cl2 is reported. They are characterized by vibrational, NMR and UV-VIS spectroscopic measurements. Ph3Si—S4—SiPh3 crystallizes in space group P1 with a = 943.6(6) pm, b = 945.7(5) pm, c = 1 881.7(12) pm, α = 82.11(5)°, β = 78.95(5)°, γ = 83.15(5)° and Z = 2.
    Notes: Es wird über die Darstellung der Bis(triphenylsilyl)-sulfane Ph3Si—Sx—SiPh3 (x = 3, 4) aus Ph3SiSNa und SCl2 bzw. S2Cl2 berichtet. Ihre Charakterisierung erfolgt schwingungs-, NMR-, und UV-VIS-spektroskopisch.Ph3Si—S4—SiPh3 kristallisiert in der Raumgruppe P1 mit a = 943,6(6) pm, b = 945,7(5) pm, c = 1 881,7(12) pm, α = 82,11(5)°, β = 78,95(5)°, γ = 83,15(5)° und Z = 2.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946200605
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  • 5
    Electronic Resource
    Electronic Resource
    Darstellung und spektroskopische Charakterisierung der Fluorphosphonium-Salze X2FPSCH3+MF6- (X = Br, Cl; M = As, Sb) und XF2PSCH3+SbF6- (X = Br, Cl, F) (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 612 (1992), S. 40-44 
    Details
    ISSN: 0044-2313
    Keywords: Fluorophosphonium salts ; preparation ; vibrational spectra ; NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation and Spectroscopic Characterization of the Fluorophosphonium Salts X2FPSCH3+MF6- (X = Br, Cl; M = As, Sb) and XF2PSCH3+SbF6- (X = Br, Cl, F)The preparation of the fluorophosphonium salts X2FPSCH3+MF6- (X = Br, Cl; M = As, Sb) and XF2PSCH3+SbF6- (X = Br, Cl, F) by methylation of the corresponding thiophosphorylhalides in the system CH3F/SO2/MF5 (M = As, Sb) is reported. The new salts are characterized by their vibrational and NMR spectra.
    Notes: Es wird über die Darstellung der Fluorphosphoniumsalze X2FPSCH3+MF6- (X = Br, Cl; M = As, Sb) and XF2PSCH3+SbF6- (X = Br, Cl, F) durch oxidative Methylierung der korrespondierenden Thiophosphorylhalogenide mit dem System CH3F/SO2/MF5 (M = As, Sb) berichtet. Die Salze werden durch ihre Schwingungs- und NMR-Spektren charakterisiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926120108
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  • 6
    Electronic Resource
    Electronic Resource
    The reaction of XeF+MF6- (M = As, Sb) with sulfuranes; preparation of CF3(O)F2+SbF6- and (CF3)2SOXeF+SbF6- (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 612 (1992), S. 35-39 
    Details
    ISSN: 0044-2313
    Keywords: CF3S(O)F2 +SbF6- ; (CF3)2SOXeP+SbF6- ; preparation ; vibrational spectra ; NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Die Reaktion von XeF+SbF6- mit Sulfuranen; Präparation von CF3S(O)F2+SbF6- und (CF3)2SOXeF+SbF6-CF3S(O)F, (CF3)2SO, CF3SF3, (CF3)2SF2, und SF4 reagieren in unterschiedlicher Weise mit XeF+MF6- (M=As, Sb). Eine oxidative Fluorierung wird beobachtet beim CF3S(O)F unter Bildung des Persulfoniumsalzes CF3S(O)F2+SbF6-, während mit (CF3)2SO ein einfaches Xenon-enthaltendes Additionsprodukt (CF3)2SOXeF+SbF6- isoliert werden kann. Im Gegensatz dazu führt der Lewis-saure Charakter des XeF+ -Kations gegenüber (CF3)nSF4-n (n = 0 - 2) zu den entsprechenden Fluorsulfoniumsalzen (CF3)nSF3-n +MF6- (M=As. Sb) und XeF2.
    Notes: CF3S(O)F, (CF3)2SO, CF3SF3, (CF3)2SF2, and SF4 react in different manner with XeF+MF6- (M=As, Sb). An oxidative fluorination is observed by CF3S(O)F forming the persulfonium salt CF3S(O)F2+SbF6-, whereas by (CF3)2SO a simple addition product containing xenon can be isolated in form of the sulfonium salt (CF3)2SOXeF+SbF6-. On the contrary, the Lewis-acidic character of the XeF+-cation predominates against (CF3)nSF4-n (n = 0 - 2) leading to the corresponding fluorosulfonium salts (CF3)nSF3-n +MF6- (M=As, Sb) and XeF2.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926120107
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  • 7
    Electronic Resource
    Electronic Resource
    The Pentabromine(1+) Cation, Br5+. Local Density Functional Calculations and Vibrational Spectra (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 612 (1992), S. 51-55 
    Details
    ISSN: 0044-2313
    Keywords: Pentabromine(1+) cation ; local density functional calculations ; vibrational spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Das Pentabrom(1+)- Kation, Br5+. Berechnungen mit der Dichtefunktional-Methode und SchwingungsspektrenFür das Br5+-Kation werden mit der Dichtefunktional-Methode Geometrie, Schwingungsspektren und Landungsverteilung berechnet. Das freie Ion hat in der gauche-Konfiguration die niedrigste Energie. Die drei mittleren Br-Atome bilden danach einen Winkel von 168,6° und der Diederwinkel der beiden terminalen Br-Atome beträgt 82°. Diese Konfiguration steht damit im Gegensatz zu der planaren trans-Konfiguration mit C2h-Symmetrie, die für Br5+ im Br5+ MF6- (M = As, Sb) durch Röntgenbeugung gefunden wurden. Die geringe Energiedifferenz von 1,2 kcal mol-1 zwischen der gauche- und trans-Konfiguration, verbunden mit Kristallpackungseffekten, könnten für die trans-Konfiguration von Br5+ im festen Br5+MF6- verantwortlich sein.Um den wahrscheinlichsten der bereits publizierten sich stark unterscheidenden Frequenzsätze, zu bestimmen, wurden die berechneten Schwingungsspektren herangezogen.Im Gegensatz zu früheren STO-3G-Rechnungen für Cl5+, können mit diesen LDF-Rechnungen für Br5+ und Cl5+ Ladungsverteilungen wiedergegeben werden, die mit einem früher vorgeschlagenen einfachen „valencebond-model“ für Pentahalogen(1+)-Kationen übereinstimmen.
    Notes: The geometry, vibrational spectra and charge distribution of Br5+ were calculated by the use of the local density functional (LDF) method. The results show that for free Br5+ the lowest energy configuration is a skew structure with the three central Br atoms forming an angle of 168.6° und the two terminal Br atoms exhibiting a dihedral angle of 82°. This skew configuration is in contrast to the planar trans configuration of C2h symmetry found for Br5+ in solid Br5+MF6- (M = As, Sb). The small energy difference of 1.2 kcal mol-1 between the skew and the trans configurations, combined with crystal packing effects, can account for the planar trans configuration of Br5+ in solid Br5+MF6-. The computed vibrational spectra were used to select the most likely set from three sets of previously published and widely diverging spectra. Contrary to previous STO-3G calculations for Cl5+, the present LDF calculations for Br5+ and Cl5+ result in charge distributions which agree with a previously proposed simple valence bond model for pentahalogen(1+) cations.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926120110
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  • 8
    Electronic Resource
    Electronic Resource
    Die Darstellung der N-Methyl-halogennitrilium-Salze XCNCH3+MF6- (X = Cl, Br, I; M = As, Sb) und der N-Methyl-trifluoracetonitrilium-Salze CF3CNCH3+MG6- (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 613 (1992), S. 93-97 
    Details
    ISSN: 0044-2313
    Keywords: Methylnitrilium salts ; preparation ; vibrational spectra ; NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of N-Methylhalidonitrilium Salts XCNCH3+MF6- (X = Cl, Br, I; M = As, Sb) and the N-Methyl-trifluoroacetonitrilium Salts CF3CNCH3+MF6-The N-methyl-halidonitrilium salts XCNCH3+MF6- (X = Cl, Br, I; M = As, Sb) are synthesized by methylation of cyanogen halides with CH3F/MF5 in SO2 at low temperatures.The N-methyl-trifluoroacetonitrilium salts CF3CNCH3+MF6- (M = As, Sb) are formed analogous with trifluoroacetonitrile. All salts are characterized by vibrational and NMR spectroscopy.
    Notes: Die N-Methyl-halogennitrilium-Salze XCNCH3+MF6- (X = Cl, Br, I; M = As, Sb) werden aus Halogenocyanen durch Methylierung mit CH3F/MF5 in SO2 bei tiefer Temperatur synthetisiert. Die Darstellung der N-Methyl-trifluoracetonitrilium-Salze CF3CNCH3+MF6- (M = As, Sb) erfolgt analog ausgehend von Trifluoracetonitril. Alle Salze werden durch Schwingungs- und NMR-Spektren charakterisiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926130116
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  • 9
    Electronic Resource
    Electronic Resource
    Über die Kristallstruktur von (C6H5)3SiSH und (C6H5)3SiSBr und die Darstellung des Iodsulfans (C6H5)3SiSI (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 877-884 
    Details
    ISSN: 0044-2313
    Keywords: triphenylsilanesulfenylbromide and -iodide ; triphenylsilanthiol ; preparation ; vibrational spectra ; UV-VIS spectra ; single crystal X-ray structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of (C6H5)3SiSH and (C6H5)3SiSBr and the Preparation of the Iodosulfane (C6H5)3SiSIThe preparation of the halogenosulfanes Ph3SiSBr and Ph3SiSI from Ph3SiSH and N-halogenosuccinimide is reported. They are characterized by vibrational spectroscopic measurements. Ph3SiSBr crystallizes in space group P1 with a = 899.3(8) pm, b = 941.3(7) pm, c = 1 051.4(7) pm, α = 109.88(5)°, β = 99.23(6)°, γ = 96.78(6)° and Z = 2. Ph3SiSH crystallizes in space group P21/c with a = 1 879.4(8), b = 966.3(5), c = 1 845.2(9), β = 107.84(4), Z = 8. The halogenosulfanes decompose in polar solvents by formation of sulphur and triphenylsilanhalide.
    Notes: Es wird über die Darstellung der Halogensulfane Ph3SiSBr und Ph3SiSI aus Ph3SiSH und N-Halogensuccinimid berichtet. Ihre Charakterisierung erfolgt schwingungsspektroskopisch. Das Ph3SiSBr kristallisiert in der Raumgruppe P1 mit a = 899,3(8) pm, b = 941,3(7) pm, c = 1 051,4(7) pm, α = 109,88(5)°, β = 99,23(6)°, γ = 96,78(6)° und Z = 2, das Ph3SiSH in der Raumgruppe P21/c mit a = 1 879,4(8) b = 966,3(5), c = 1 845,2(9), β = 107,84(4), Z = 8. Die Halogensulfane zerfallen in polaren Lösungsmitteln unter Schwefeleliminierung zu Triphenylsilylhalogeniden.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936190512
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  • 10
    Electronic Resource
    Electronic Resource
    Darstellung der Halogennitrilium-Salze XCNH+MF6- (X = Cl, Br, I; M = As, Sb) und der Trifluoracetonitrilium-Salze CF3CNH+MF6- (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 617 (1992), S. 143-147 
    Details
    ISSN: 0044-2313
    Keywords: Nitrilium salts ; preparation ; vibrational spectra ; NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of the Halogenonitrilium Salts XCNH+MF6- (X = CI, Br, I; M = As, Sb) and the Trifluoroacetonitrilium Salts CF3CNH+MF6-The halogenonitrilium salts XCNH+MF6- (X = CI, Br, I; M = As, Sb) are synthesized by protonation of cyanogen halides in the superacide system HF/MF5 at low temperature. The synthesis of trifluoroacetonitrilium salts CF3CNH+MF6- (M = As, Sb) is proceeded analogous with trifluoroacetonitrile. All salts are characterized by vibrational and NMR spectroscopy.
    Notes: Die Halogennitrilium-Salze XCNH+MF6- (X = Cl, Br, I; M = As, Sb) werden aus Halogencyanen durch Protonierung mit dem supersauren System HF/MF5 bei tiefer Temperatur dargestellt. Die Synthese der Trifluoracetonitrilium-Salze CF3CNH+MF6- (M = As, Sb) erfolgt analog aus Trifluoracetonitril. Alle Salze werden durch Schwingungs und NMR-Spektren charakterisiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926170125
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