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  • 1
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    PANGAEA
    In:  Supplement to: Karstens, Ute; Schwingshackl, Clemens; Schmithüsen, Dominik; Levin, Ingeborg (2015): A process-based 222Rn flux map for Europe and its comparison to long-term observations. Atmospheric Chemistry and Physics, 15, 12845-12865, https://doi.org/10.5194/acp-15-12845-2015
    Publication Date: 2023-01-13
    Description: A high-resolution 222Radon (222Rn) flux map for Europe was developed, based on a parameterization of 222Rn production and transport in the soil. The 222Rn exhalation rate is parameterized based on soil properties, uranium content, and modelled soil moisture from two different land-surface reanalysis data sets. Spatial variations in exhalation rates are primarily determined by the uranium content of the soil, but also influenced by soil texture and local water table depth. Temporal variations are related to soil moisture variations as the molecular diffusion in the unsaturated soil zone depends on available air-filled pore space. Monthly 222Rn exhalation rates from European soils were calculated with a nominal spatial resolution of 0.083° x 0.083°. The two realizations of the 222Rn flux map, based on the different soil moisture data sets, both realistically reproduce the observed seasonality in the fluxes but yield considerable differences for absolute flux values. The mean 222Rn flux from soils in Europe is estimated to be 10 mBq/m**2/s (ERA-Interim/Land soil moisture) or 15 mBq/m**2/s (GLDAS-Noah soil moisture) for the period 2006-2010. The 222Rn flux maps for Europe are available for the application in atmospheric transport studies, e.g to evaluate the performance of atmospheric transport models.
    Keywords: Europe; File name; File size; Uniform resource locator/link to file
    Type: Dataset
    Format: text/tab-separated-values, 6 data points
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  • 2
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    PANGAEA
    In:  Supplement to: Weller, Rolf; Levin, Ingeborg; Schmithüsen, Dominik; Nachbar, Mario; Asseng, Jölund; Wagenbach, Dietmar (2014): On the variability of atmospheric 222Rn activity concentrations measured at Neumayer, coastal Antarctica. Atmospheric Chemistry and Physics, 14(8), 3843-3853, https://doi.org/10.5194/acp-14-3843-2014
    Publication Date: 2023-05-15
    Description: We report on continuously measured 222Rn activity concentrations in near-surface air at Neumayer Station in the period 1995-2011. This 17-year record showed no long-term trend and has overall mean ± standard deviation of (0.019 ± 0.012) Bq/m**3. A distinct and persistent seasonality could be distinguished with maximum values of (0.028 ± 0.013) Bq/m**3 from January to March and minimum values of (0.015 ± 0.009) Bq/m**3 from May to October. Elevated 222Rn activity concentrations were typically associated with air mass transport from the Antarctic Plateau. Our results do not support a relation between enhanced 222Rn activity concentrations at Neumayer and cyclonic activity or long-range transport from South America. The impact of oceanic 222Rn emissions could not be properly assessed but we tentatively identified regional sea ice extent (SIE) variability as a significant driver of the annual 222Rn cycle.
    Keywords: Air chemistry observatory; Atmospheric Chemistry @ AWI; AWI_AC; DATE/TIME; Date/time end; Dronning Maud Land, Antarctica; Duration, number of days; HEIGHT above ground; Neumayer_based; Neumayer_SPUSO; NEUMAYER III; Radon-222 activity; SPUSO
    Type: Dataset
    Format: text/tab-separated-values, 17121 data points
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 370 (1994), S. 201-203 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The atmospheric 14CO2 activity has undergone large excur-sions since the beginning of nuclear bomb tests (Fig. \a and 6, solid lines). After the Test Ban treaty in 1962 the bomb 14C signal in the atmosphere is declining because of 14CO2 exchange with the ocean and the other carbon reservoirs. The ...
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-0662
    Keywords: Atmospheric background concentrations ; ozone ; carbondioxide ; carbon isotopes ; methane ; optical thickness ; North Atlantic ; long-range transport
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract First results of baseline observations from the new BAPMoN station Tenerife give information about the atmospheric background in this latitude of about 25° N in the North Atlantic. The influence of the meridional exchange with the northern part of the hemisphere as well as transport from the African continent is evident. Changes of air mass are strongly reflected in the concentration records of carbon dioxide, methane, and ozone depending on the seasonal and meridional distribution of these components. Transport of Sahara dust results in an increase of optical thickness and an ozone depletion. According to the seasonal frequency of characteristic transport conditions, these influences are reflected in the annual cycle of the records.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 2020-05-08
    Description: The use of the noble gas radon (222Rn) as a tracer for different research studies, for example observation-based estimation of greenhouse gas (GHG) fluxes, has led to the need of high-quality 222Rn activity concentration observations with high spatial and temporal resolution. So far a robust metrology chain for these measurements is not yet available. A portable direct atmospheric radon monitor (ARMON), based on electrostatic collection of 218Po, is now running at Spanish stations. This monitor has not yet been compared with other 222Rn and 222Rn progeny monitors commonly used at atmospheric stations. A 3-month intercomparison campaign of atmospheric 222Rn and 222Rn progeny monitors based on different measurement techniques was realized during the fall and winter of 2016–2017 to evaluate (i) calibration and correction factors between monitors necessary to harmonize the atmospheric radon observations and (ii) the dependence of each monitor's response in relation to the sampling height and meteorological and atmospheric aerosol conditions. Results of this study have shown the following. (i) All monitors were able to reproduce the atmospheric radon variability on a daily basis. (ii) Linear regression fits between the monitors exhibited slopes, representing the correction factors, between 0.62 and 1.17 and offsets ranging between −0.85 and −0.23 Bq m−3 when sampling 2 m above ground level (a.g.l.). Corresponding results at 100 m a.g.l. exhibited slopes of 0.94 and 1.03 with offsets of −0.13 and 0.01 Bq m−3, respectively. (iii) No influence of atmospheric temperature and relative humidity on monitor responses was observed for unsaturated conditions at 100 m a.g.l., whereas slight influences (order of 10−2) of ambient temperature were observed at 2 m a.g.l. (iv) Changes in the ratio between 222Rn progeny and 222Rn monitor responses were observed under very low atmospheric aerosol concentrations. Results also show that the new ARMON could be useful at atmospheric radon monitoring stations with space restrictions or as a mobile reference instrument to calibrate in situ 222Rn progeny monitors and fixed radon monitors. In the near future a long-term comparison study between ARMON, HRM, and ANSTO monitors would be useful to better evaluate (i) the uncertainties of radon measurements in the range of a few hundred millibecquerels per cubic meter to a few becquerels per cubic meter and (ii) the response time correction of the ANSTO monitor for representing fast changes in the ambient radon concentrations.
    Print ISSN: 1867-1381
    Electronic ISSN: 1867-8548
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 6
    Publication Date: 1988-11-01
    Print ISSN: 0167-7764
    Electronic ISSN: 1573-0662
    Topics: Chemistry and Pharmacology , Geosciences
    Published by Springer
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  • 7
    Publication Date: 1995-01-01
    Description: We present here first results of 14CO2 monitoring at two sampling sites in the equatorial region of the South American continent (station Aychapicho, Ecuador and station Llano del Hato, Venezuela). We also include the data for two other stations representing undisturbed marine atmosphere at mid-latitudes of both hemispheres, far from large continental sources and sinks of CO2 (station Izaña, Tenerife, Spain and station Cape Grim, Tasmania). Between 1991 and 1993, 14CO2 levels in the tropical troposphere were generally higher by 2–5‰ when compared to mid-latitudes of both hemispheres. This apparent maximum of 14C in the tropics can be explained by two major factors: 1) emissions of 14C-free fossil fuel CO2, restricted mainly to mid-latitudes of the northern hemisphere; and 2) 14C depletion due to gas exchange with circumpolar Antarctic upwelling water, influencing mainly mid- and high southern latitudes. The δ14C record so far available for the Aychapicho station provides direct evidence for a regional reduction of atmospheric 14CO2 levels due to gas exchange with 14C-depleted equatorial surface ocean in the upwelling regions and dilution with the 14C-depleted CO2 released in these areas. Recurrent ENSO events, turning on and off the 14C-depleted CO2 source in the tropical Pacific, lead to relatively large temporal variations of the atmospheric 14C level in this region.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 8
    Publication Date: 1987-01-01
    Description: A technique for 14C measurement of small volume (0.5L) oceanic water samples by Accelerator Mass Spectrometry (AMS) is described. Samples were taken from a CTD/rosette system used for standard hydrographic work. After CO2 extraction and target preparation, the samples were measured at the Zürich tandem accelerator facility. On the basis of 14C data from samples collected on a station in the northern Weddell Sea, the precision of the measurements is estimated to ca ±8‰. The error in the present AMS results is dominated by the statistical error in 14C detection. From results of duplicate targets, it is concluded that a precision of ±5° can be reached. The 14C data are discussed in relation to the Weddell Sea hydrography.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 9
    Publication Date: 1980-01-01
    Description: 14C measurements on continuous weekly samples of atmospheric CO2 and hydrocarbons, collected in a rather densely populated area are presented. The deviation of the measured 14C data from the clean air level is primarily due to CO2 from the combustion of fossil fuels. This is confirmed by fossil fuel admixture estimates individually calculated with an atmospheric dispersion model. Up to 10 percent admixture is predicted by this model and observed from the 14C shift for weekly averages, particularly during the winter season. Natural CO2 admixture due to soil respiration, however, even in winter, is of the same order of magnitude, but much larger in the warm season: the considerable variations in CO2 concentration in summer are almost exclusively controlled by natural sources. Using tree leaf samples, we have been able to identify boiling water reactors (BWR) as weak sources of 14CO2. Atmospheric samples taken in the environment of the pressurized water reactors (PWR) Biblis show that the 14C release of these reactors is primarily in the form of hydrocarbon 14C. The source strength of the various power plants, calculated on the basis of our observations in their environment, ranges from 0.5 to 7Ci per year.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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  • 10
    Publication Date: 1989-01-01
    Description: Observations of 14C in atmospheric CO2 at four different sites in central Europe, Heidelberg, Westerland, Schauinsland and Jungfraujoch have enabled us to determine individual fossil-fuel contributions to atmospheric CO2 concentration. The data clearly show a decrease of fossil-fuel CO2 with distance from anthropogenic source regions. At Heidelberg during winter we observe 14C/12C ratios up to 10% lower than at the clean air mountain station Jungfraujoch in the Swiss Alps, corresponding to an anthropogenic CO2 contamination level of ca 10% at the Heidelberg site. The Schauinsland and Westerland winter fossil-fuel CO2 concentrations are only ca 1.5 and 2% of the mean concentration, respectively. Our results indicate a strong seasonality in the European fossil-fuel CO2 source with ca 50% lower CO2 emissions during summer if compared to winter fossil-fuel CO2 release. This effect may significantly contribute (by 1–2 ppm) to the observed annual cycle of atmospheric CO2 concentration in northern mid-latitudes.
    Print ISSN: 0033-8222
    Electronic ISSN: 1945-5755
    Topics: Archaeology , Energy, Environment Protection, Nuclear Power Engineering , Geosciences
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