ISSN:
0044-2313
Keywords:
Aminoarsanes
;
cleavages of As—N bond
;
hetrocyclic compounds containing As, S, O, N and C
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Reaction of Bis(bis-dimethylamino-arsino)methane and Bis(dimethylamino-arsino)methane with Aminoalcohols, Diols, Mono- and DithiodiolsThe reactions of the aminoarsanes (Me2N)2As—CH2—As(NMe2)2 and (Me2N)(Me)As—CH2—As(Me)(NMe2) with aminoalcohols and diols result in the cleavage of the As—N bond. The stoichiometry of the reactions decides, wether cyclic or acyclic compounds are obtained.
Notes:
Die Reaktion der beiden Aminoarsane (Me2N)2As—CH2—As(NMe2)2 und (Me2N)(Me)As—CH2—As(Me)(NMe2) mit Aminoalkoholen und Diolen führt zur Spaltung der As—N-Bindung. Die Stöchiometrie der Reaktionen entscheidet darüber, ob cyclische oder acyclische Produkte erhalten werden.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19916050118
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