ALBERT

Description: Distribution of intact polar membrane lipids (IPLs) in different soil profiles and in fluvial and marine sediments along the pathway of transport in a small catchment in the high Arctic at Ny-Ålesund, Svalbard (79N, 12E).

Description: Distribution of bacteriohopanepolyols (BHPs) in different soil profiles and in fluvial and marine sediments along the pathway of transport in a small catchment in the high Arctic at Ny-Ålesund, Svalbard (79N, 12E).

Description: Distribution of elemental data (TOC, N, C/N) in different soil profiles and in fluvial and marine sediments along the pathway of transport in a small catchment in the high Arctic at Ny-Ålesund, Svalbard (79N, 12E).

Description: The age of organic material discharged by rivers provides information about its sources and carbon cycling processes within watersheds. While elevated ages in fluvially-transported organic matter are usually explained by erosion of soils and sediments, it is commonly assumed that mainly young organic material is discharged from flat tropical watersheds due to their extensive plant cover and high carbon turnover. Here we present compound-specific radiocarbon data of terrigenous organic fractions from a sedimentary archive offshore the Congo River in conjunction with molecular markers for methane-producing land cover reflecting wetland extent in the watershed. We find that the Congo River has been discharging aged organic matter for several thousand years with increasing ages from the mid- to the Late Holocene. This suggests that aged organic matter in modern samples is concealed by radiocarbon from nuclear weapons testing. By comparison to indicators for past rainfall changes we detect a systematic control of organic matter sequestration and release by continental hydrology mediating temporary carbon storage in wetlands. As aridification also leads to exposure and rapid remineralization of large amounts of previously stored labile organic matter we infer that this process may cause a profound direct climate feedback currently underestimated in carbon cycle assessments.

Description: Bacteriohopanepolyols (BHPs) are ubiquitous bacterial membrane lipids, encountered in soils, river and marine suspended particulate matter (SPM) and sediments. Their abundance and distribution provides a direct means to identify bacterial inputs and can be used to trace soil-derived bacterial organic matter (OM) and in some cases the presence of bacterial groups and their activities in aquatic systems. We have studied the BHP distribution in the SPM of a major Siberian River (Yenisei River) that crosses a large latitudinal gradient, draining a large part of Mongolia and Siberian Russia. The Yenisei River is the main river to flow into the Kara Sea, a shelf sea of the Arctic Ocean. We show that the BHP distribution and concentration of SPM and surface sediments of the Yenisei Outflow in the Kara Sea allow to trace soil-marker BHPs and evaluate the performance of the R'soil index, a proxy developed to trace bacterial soil-derived OM. Soil-marker BHPs are present in the Yenisei River, and their concentration decreases from the Yenisei River Outflow into the offshore marine sediments. The R'soil correlates well with an independent proxy for bacterial OM, the BIT-index (r**2 = 0.82) and has a moderate correlation with the d13Corg values, a bulk OM proxy for terrigenous input (r**2 = 0.44). Consequently, the R'soil index performs well in the Kara Sea, strengthening its application for tracing bacterial OM in the Arctic Ocean, both in modern and downcore sediments. Furthermore, a suite of BHPs that are characteristic for methanotrophic bacteria, i.e. 35-aminobacteriohopane-30,31,32,33,34-pentol (aminopentol) and 35-aminobacteriohopane-31,32,33,34-tetrol (aminotetrol), is encountered in the Yenisei Outflow sediments. These components are partly sourced from terrigenous sources, but are likely also produced in-situ in the marine sediments. The distribution of the pentafunctionalized cyclitol ether BHP in the marine systems is noteworthy, and indicates that it can possibly be applied as a marker for cyanobacterial biomass in marine sediments.

Description: Centennial-scale records of sea-surface temperature and opal composition spanning the Last Glacial Maximum and Termination 1 (circa 25-6 ka) are presented here from Guaymas Basin in the Gulf of California. Through the application of two organic geochemistry proxies, the UK37' index and the TEX86H index, we present evidence for rapid, stepped changes in temperatures during deglaciation. These occur in both temperature proxies at 13 ka (~3°C increase in 270 years), 10.0 ka (~2°C decrease over ~250 years) and at 8.2 ka (3°C increase in 〈200 years). An additional rapid warming step is also observed in TEX86H at 11.5 ka. In comparing the two temperature proxies and opal content, we consider the potential for upwelling intensity to be recorded and link this millennial-scale variability to shifting Intertropical Convergence Zone position and variations in the strength of the Subtropical High. The onset of the deglacial warming from 17 to 18 ka is comparable to a "southern hemisphere" signal, although the opal record mimics the ice-rafting events of the north Atlantic (Heinrich events). Neither the modern seasonal cycle nor El Niño/Southern Oscillation patterns provide valid analogues for the trends we observe in comparison with other regional records. Fully coupled climate model simulations confirm this result, and in combination we question whether the seasonal or interannual climate variations of the modern climate are valid analogues for the glacial and deglacial tropical Pacific.