ALBERT

Notes: A proposal is made to standardise the reporting of Ca isotope data to the δ44Ca/40Ca notation (or δ44Ca/42Ca) and to adopt NIST SRM 915a as the reference standard.

Notes: The Austin Glen Member of the upper Middle Ordovician Normanskill Formation is a sandstone-shale flysch succession deposited in the foreland of the Taconian Orogen. Petrographic, major and trace element, and Nd–Pb isotopic data provide substantial constraints on its provenance. Lack of K-feldspar and paucity of plagioclase, in addition to the dominance of sedimentary rock fragments, indicate that the source was dominated by recycled, sedimentary components. Major and trace element data support this conclusion and indicate that the provenance of both shales and sandstones was the same. No evidence of an ophiolitic or volcanic component was observed. Interpretation of Nd isotopic characteristics are complicated by a partial resetting of the Nd isotope system at about the time of sedimentation but indicate that the provenance of the Austin Glen Member had a long-term history of light rare earth element (LREE) enrichment (average TDM = 1·8 Ga). Furthermore, Nd isotopic compositions are extremely homogeneous (ɛNd = –8·1 ± 0·6; 1 s.d.; n = 23) at 450 Ma, the approximate depositional age, indicating either a single source or very well-mixed sources. 207Pb/204Pb ratios are variable but within the range of Pb isotopic compositions typically described as Grenvillian. The range of 207Pb/204Pb is greater than expected for the range of 206Pb/204Pb and suggests an additional component of Pb, possibly introduced during diagenesis. The immediate source of the Austin Glen Member may have been the accretionary prism that developed as older sediments of the Laurentian margin were scraped off the basin floor, incorporated within the accretionary prism and shed into the basin. No evidence indicating the arrival of an undifferentiated island arc or continental fragment during the Taconian Orogeny has been found. The data acquired during this study can be explained almost exclusively by Grenville Province source components but with possible additional contributions from older Laurentian terranes and Late Proterozoic rift volcanics that are not readily quantified but likely to have been minor. Accordingly, we conclude that the Taconian Orogeny in New England involved either: (1) a continental arc that involved exclusively Laurentia; (2) collision of a continental block with identical geochemical characteristics as Laurentia; or (3) essentially no detritus from any exotic colliding block (island arc or continental fragment) reached the foreland basin at the time of Austin Glen deposition.

Notes: Clastic sedimentary rocks, deposited on eastern North America in response to the Taconian Orogeny, commonly have Sm/Nd isotope relationships indicating substantial isotope disturbance near or subsequent to the time of sedimentation that may be associated with severe depletion in light rare earth elements (LREE). Affected units [Normanskill Formation (Austin Glen and Pawlet Members), Frankfort Formation and Perry Mountain Formation] are widely separated both geographically (western New York to western Maine) and stratigraphically (Middle Ordovician to Silurian). A model is proposed for the most likely explanation of the observed REE and Sm/Nd isotope relationships involving a two-stage process. In the first stage, REE are redistributed on a mineralogical scale (dissolution/precipitation on a sample scale) often with the involvement of REE-enriched trace phases such as apatite and monazite. This stage typically takes place during diagenesis but may also take place later during metamorphism and/or recent weathering, and results in isotope re-equilibration on a sample scale. The second stage occurs when one or more of these phases is redissolved and REE are transported on large advective scales. Where LREE-enriched phases are involved, this gives rise to LREE depletion in whole rocks. The timing of this second stage cannot be constrained from Sm/Nd isotope data and may take place at any time subsequent to the isotope re-equilibration. Such complex histories of REE redistribution may result in serious errors in estimating Nd model ages but not in estimating the Nd isotope composition at the age of sedimentation. Thus, Sm/Nd ratios even of unmetamorphosed sedimentary rocks have to be carefully evaluated before the calculation of depleted mantle model ages for the provenance.