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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Environmental science & technology 17 (1983), S. 479-484 
    ISSN: 1520-5851
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Chemical reviews 76 (1976), S. 801-826 
    ISSN: 1520-6890
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 79 (1975), S. 677-681 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 79 (1975), S. 7-11 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
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  • 5
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 48 (1997), S. 61-68 
    ISSN: 1573-0867
    Keywords: biomass burning ; deforestation ; N-fertilization ; NO soil fluxes ; soil plowing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Changes in land use driven by the increasing demand of food are affecting the fluxes of trace gases to the atmosphere. The more important human activities that affect NO soil fluxes are: deforestation, intensification of agricultural practices, and biomass burning. In this review emphasis is given to identifying the physicochemical and biological processes involved in the changes, and no attempt to quantify their contribution to global or regional NO budgets is made. Conversion of tropical forest to pasture is occurring very rapidly. An increase of the NO emission is observed immediately after deforestation (1–5 years) followed by a significant decrease (below forest levels) in old pastures and secondary successional forests. It seems that deforested tropical areas produce, in the long term, less NO than primary forests. The observed changes are not completely understood, but are most likely driven by the availability of exchangeable nitrogen and the bacteria' population. Soil plowing and fertilization are important factors that affect NO fluxes in agricultural soils. Plowing increases soil porosity and aeration, as well increasing the surface area that is exposed to the atmosphere. These physical changes increase the production of soil nitrate, and the escape efficiency of NO from the soil, enhancing NO fluxes. The emission of NO from fertilized soils depends on many variables: type of fertilizer (i.e. ammonium, nitrate), the structure of the soil microbial community (e.g., populations of nitrifiers and denitrifiers), meteorogical conditions (e.g. soil moisture and temperature), and soil management (e.g. plowing). A combination of these factors should explain the large range reported for the fraction of N-fertilizer that is emitted as NO to the atmosphere. Measurements made in diverse ecosystems show that vegetation burning enhances NO soil emissions. However, it seems that different processes, which are not well understood, occur at the various sites; e.g., in the tropical savannah, enhanced emissions, from dry soils, are observed immediately after burning, whereas in Californian chaparral burned dry soils emit on average less than the unburned plots, and the fluxes only increase after soil wetting. Changes in the physical conditions of the soil surface and N availability are the most likely factors that explain the increased fluxes.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 2 (1985), S. 377-385 
    ISSN: 1573-0662
    Keywords: Tropospheric ozone ; ozone in the tropical savannah ; background ozone in Venezuela
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract A one-year set of surface ozone measurements in a four-station network located in the Venezuelan savannah is reported. The diurnal ozone variation is typical of continental stations with a maximum in the afternoon, when vertical turbulent mixing is strongest. The annual O3 average concentration, based on the monthly averages of daily maxima, was 17±2 ppb, which is in good agreement with values reported for similar latitudes. The boundary-layer ozone levels did not fall below 8 ppb, in contrast with previous sporadic measurements made in tropical latitudes. No evidence was found that mesoscale O3 downdrafts in the ITCZ in the South American continent are an important source of surface ozone. Finally, it is suggested that the relatively high ozone levels observed at the end of the dry season are probably of photochemical origin.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 35 (2000), S. 249-272 
    ISSN: 1573-0662
    Keywords: ozone ; tropical atmosphere ; boundary layer ozone ; biomass burning ; Venezuelan savannah
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract In recent field campaigns, boundary layer ozone concentrations were measuredat different sites in the Orinoco river basin (mainly savannahs) and nearbylocations (cloud forest and coastal sites), during dry and wet seasons. Theresults provide a comprehensive description of boundary layer ozone in atropical region north of the equator where scarce information is available.Ozone measurements were made using photometric ozone analyzers. In thesavannah region, ozone profiles (up to 1000 m) were also obtained usingelectrochemical concentration cell sondes, launched in a tethered balloon.The results, in comparison with other parts of the world, confirm the lowvalues for the concentration of ozone in the boundary layer of the studyregion. Throughout the entire region (marine, coastal, and continental areas),higher concentrations were produced during the dry season (20–30 ppbv)than during the wet season (13–17 ppbv), likely due to the photochemicalproduction of ozone from biomass burning emissions. This seasonal variationobserved in the boundary layer contrasts with satellite data, that show highertotal tropospheric ozone columns during the wet season in the 0–15°Nregion; this means that the ozone annual cycles in the boundary layer and freetroposphere are out of phase.At the most pristine continental sites in the southern part of Venezuela,quite a `peculiar' diurnal variation was observed, with maximum concentrationsin the morning and a steady decrease of ∼0.6 ppbv hr-1 duringthe hours of high solar irradiation. Although dynamic aspects cannot be ruledout, the daytime ozone decrease, which cannot be explained by thewell-established `classical' continental O3 sinks, suggests thatin this region part of the ozone consumption is caused byHO x cycles at low NO x levels. Futurestudies to elucidate the causes of the daytime ozone decrease at thesecontinental sites should be undertaken.
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  • 9
    ISSN: 1573-0662
    Keywords: Savannah atmosphere ; vegetation burning ; soluble particles ; particles size distributions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The results presented are the first complete analysis of inorganic soluble ions in a tropical savannah region. Atmospheric particles were collected in six rural Venezuelan savannah sites. Concentrations and size distribution of NO3 −, SO4 2-, CI−, PO4 3-, NH4 +, Na+, K+, Ca2+ and Mg2+ were determined in samples collected with Hi Vol samplers equipped with five-stage cascade impactors. Concentrations were higher in the dry season, with a maximum during the burning periods. Using Na+ as a reference, the results show a deficit of Cl− and, with the exception of Mg2+, an enrichment of all other ions with respect to marine aerosols. Significant variations were observed in particle-size distribution between different periods. Various pairs of ions present similar size distributions: SO4 2- and NH4 +; Cl− and Na+; PO4 3- and K+; Ca2+, Mg2+ and NO3 −; indicating that the ions were produced by the same source and/or were involved in similar atmospheric processes. Possible primary sources, the gas-to-particle atmospheric process, environmental implication of long-range transport of nutrients during dry seasons, etc., are discussed.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 11 (1990), S. 245-254 
    ISSN: 1573-0662
    Keywords: Nitric acid ; ammonia ; tropical atmosphere ; vegetation burning
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Gaseous nitric acid and ammonia were sampled with annular denuders at a forest savannah site from April to December 1987. The analysis of the extract was made spectrophotometrically and by a selective electrode for NO3 − and NH4 +, respectively. Higher concentrations were observed during the vegetation burning period at the end of the dry season. In the studied savannah area, large soil emissions of NO occur during the rainy season, although very low concentrations of HNO3 (0.035 ppb) and also of particulate NO3 − (0.43 μg m-3) were observed; it is likely that NOx are lost by fast vertical transport to the upper troposphere. During the nonburning period, the average concentration of NH3 was 2.7 ppb, which is much lower than values given in the literature for the tropical America atmosphere. The concentrations of HNO3 and NH3 were always below the values needed to produce ammonium nitrate aerosols.
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