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  • 11
    Publication Date: 2004-08-23
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 12
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    Geological Society of America (GSA)
    In: Geology
    Publication Date: 2016-06-30
    Description: Naturally occurring Cr(VI) has been ascribed to terrestrial Cr(III) oxidation by Mn (di)oxides, generated through reaction of Mn(II) with molecular oxygen (O 2 ). However, hydrogen peroxide (H 2 O 2 ) is a potential oxidant of Cr(III) that may form in serpentinization (high H 2 , low O 2 ) systems where chromite [i.e., the main mineralogical source of Cr(III)] is abundant. Accordingly, here we evaluate H 2 O 2 and chromite interactions in serpentinization systems to determine pathways of Cr(III) oxidation that alters the current paradigm of O 2 -dependent oxidation. Field observations support that metastable H 2 O 2 and Cr(VI) are present in serpentinization-related fluids relatively absent of O 2 . Further, laboratory experiments demonstrate and support that H 2 O 2 is a kinetically facile oxidant of chromite, especially under alkaline conditions, which provides a variety of alternative means by which Cr(VI) may be generated and supplied to the oceans not directly linked to atmospheric O 2 . Thus, Cr(III) oxidation pathways, and their influence on the Cr isotopic record, must account for anoxic Cr(III) oxidation in serpentinization systems as well as a variety of H 2 O 2 -induced Cr(III) oxidation pathways that may occur in both terrestrial and marine systems.
    Print ISSN: 0091-7613
    Electronic ISSN: 1943-2682
    Topics: Geosciences
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  • 13
    Publication Date: 2015-10-02
    Description: Numerical calculations assuming linear elasticity by Böse et al. (2014) indicate that an M w  7.75 earthquake on the Newport–Inglewood fault would cause 5 m/s of horizontal peak ground velocity (PGV) within the Los Angeles basin. However, the dynamic strain from this event would take much of the uppermost few hundred meters of basin rock beyond its frictional elastic limit. Stiff quartz-rich beds within the basin are fragile geological features that would fail and crack before the rest of the clay-rich rock mass. Repeated cracking would reduce the shear modulus of the quartz-rich beds to the level that cracking barely occurred during strong events. When interpreted in this way, data from such stiff beds near the Los Angeles International Airport indicate past PGV of ~1.6 m/s, comparable with near-field records from the strike-slip 2002 Denali and 1992 Landers earthquakes. Numerical calculations capable of representing nonlinear failure within shallow bedded rocks are warranted. Online Material: Digital ROSRINE S -wave borehole logs.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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  • 14
    Publication Date: 2012-01-05
    Description: The end-Permian extinction decimated up to 95% of carbonate shell-bearing marine species and 80% of land animals. Isotopic excursions, dissolution of shallow marine carbonates, and the demise of carbonate shell-bearing organisms suggest global warming and ocean acidification. The temporal association of the extinction with the Siberia flood basalts at approximately 250 Ma is well known, and recent evidence suggests these flood basalts may have mobilized carbon in thick deposits of organic-rich sediments. Large isotopic excursions recorded in this period are potentially explained by rapid venting of coal-derived methane, which has primarily been attributed to metamorphism of coal by basaltic intrusion. However, recently discovered contemporaneous deposits of fly ash in northern Canada suggest large-scale combustion of coal as an additional mechanism for rapid release of carbon. This massive coal combustion may have resulted from explosive interaction with basalt sills of the Siberian Traps. Here we present physical analysis of explosive eruption of coal and basalt, demonstrating that it is a viable mechanism for global extinction. We describe and constrain the physics of this process including necessary magnitudes of basaltic intrusion, mixing and mobilization of coal and basalt, ascent to the surface, explosive combustion, and the atmospheric rise necessary for global distribution.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 15
    Publication Date: 2012-08-01
    Description: Analog station LUC near Lucerne, California, recorded strong motions from the nearby (1.25 km) fault rupture during the 28 June 1992 Landers mainshock. The records illustrate general issues that can arise at near-field stations. In the area of the station, weathered granite regolith with 400 m/s S -wave velocity overlies intact granite with 3000 m/s S -wave velocity. A strongly reverberating signal persisted for several seconds after near-field velocity pulse passed. Recovery of the vertical record in digital form provided calibration of resonant site properties and qualitative separation of site and source effects. The dominant signal on the vertical spectrum arises from vertically reverberating P waves in an ~13.5-m-thick layer. Horizontal spectra marginally resolve the analogous resonance for vertical S waves and coupling of vertical P waves into horizontal motion. Here, resonant amplification of a broad high-frequency band ~5–40 Hz by a factor of a few over lower frequencies sufficed to dominate acceleration records and to make velocity records jittery. Conversely, the amplitude damping times of these resonances are much less than 1 s, indicating that the time-domain decay of the acceleration signal over ~8 s is an incident-wave effect. Overall, the raw seismograms represent incident incoming high-frequency 5–40 Hz signals, but poorly resolved directional effects preclude straightforward determination of the incident body waves.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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  • 16
    Publication Date: 2016-10-08
    Description: Strong Rayleigh waves are expected to bring the shallow subsurface into frictional failure. They may nonlinearly interact with high-frequency S waves. The widely applied Drucker and Prager (1952) rheology predicts that horizontal compression half-cycle of strong Rayleigh waves will increase the strength of the subsurface for S waves and predicts that S waves with dynamic accelerations 〉1 g will reach the surface. We did not observe this effect. Rather, we observed that strong high-frequency S waves arrived at times of low Rayleigh-wave particle velocity. Physically, high-frequency S waves cause failure on horizontal fractures in which Rayleigh waves do not change the normal traction. Failure then may depend on the ratio of the shear invariant to the ambient vertical stress. The shear invariant is the square root of the sum of the squares of terms proportional to the resolved horizontal velocity from Rayleigh waves and to the resolved high-frequency dynamic acceleration from S waves. That is, an ellipse should bound resolved dynamic acceleration versus resolved particle velocity. Records from seven stations from the 2011 Tohoku earthquake and El Pedregal station during the 2015 Coquimbo Chilean earthquake exhibit this expected effect of this nonlinear interaction.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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  • 17
    Publication Date: 2018-02-10
    Description: Seafloor and passive margins gradually subside as a result of thermal contraction of the underlying lithosphere. Thermal subsidence is also an attractive mechanism for the Michigan basin. For subsidence to occur within this previously stable continental region, some mechanism is needed to heat the lithosphere and to reduce the buoyancy of the continental crust. Mechanical stretching of the lithosphere along with its crust does both at the same time. The ponding of plume material beneath the crust supplies heat, but does not directly thin the crust. The British Isles and the Congo basin provide analogies to the Michigan basin. Continental stretching before subsidence is evident within the British Isles and the Congo basin. Stretching is not obvious in Michigan, but undetected rifts extending from the Iapetus break-up margin may exist. A closed region of thin lithosphere beneath the Irish Sea may have trapped hot buoyant material from the Iceland plume; the Michigan basin may have trapped material from an Iapetus age plume near Montreal. Cratonic basins provide information on the tail of the subsidence curve, unlike more ephemeral oceanic crust and passive margins. The poorly resolved tails in the Michigan and the Congo basins are consistent with the time subsidence constant, c. 280 myr predicted by stagnant lid convection formalism.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 18
    Publication Date: 2018-02-11
    Description: Seafloor and passive margins gradually subside as a result of thermal contraction of the underlying lithosphere. Thermal subsidence is also an attractive mechanism for the Michigan basin. For subsidence to occur within this previously stable continental region, some mechanism is needed to heat the lithosphere and to reduce the buoyancy of the continental crust. Mechanical stretching of the lithosphere along with its crust does both at the same time. The ponding of plume material beneath the crust supplies heat, but does not directly thin the crust. The British Isles and the Congo basin provide analogies to the Michigan basin. Continental stretching before subsidence is evident within the British Isles and the Congo basin. Stretching is not obvious in Michigan, but undetected rifts extending from the Iapetus break-up margin may exist. A closed region of thin lithosphere beneath the Irish Sea may have trapped hot buoyant material from the Iceland plume; the Michigan basin may have trapped material from an Iapetus age plume near Montreal. Cratonic basins provide information on the tail of the subsidence curve, unlike more ephemeral oceanic crust and passive margins. The poorly resolved tails in the Michigan and the Congo basins are consistent with the time subsidence constant, c. 280 myr predicted by stagnant lid convection formalism.
    Print ISSN: 0305-8719
    Electronic ISSN: 2041-4927
    Topics: Geosciences
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  • 19
    Publication Date: 2016-12-02
    Description: Strong long-period (~3 s) seismic waves impose dynamic strains on the shallow subsurface. The dynamic strain is the dynamic velocity divided by the phase velocity of the waves. The dynamic stress is the strain times the shear modulus. A testable hypothesis is that the shear modulus of the rock self-organizes so that the rock barely fails in friction with typical imposed dynamic strains. The predicted value of stiffness divided by depth is then independent of depth for constant rock density and constant coefficient of friction with the water table at the surface. Predicted stiffness divided depth deviates from constancy for finite-water-table depth. Prior laboratory studies indicate that the coefficient of friction is lower in clay-rich rocks than in clay-free rocks. These effects provide appraisal of the concept in which hydrology and lithology are constrained. Four boreholes near Parkfield, California, qualitatively exhibit the predicted effects. There is some indication of the predicted effect of water-table depth within accumulating sediments penetrated by borehole McGlincy (MGCY) in the Santa Clara Valley of California, but the effect of clay is not well resolved, due to a dearth of clay-rich beds.
    Print ISSN: 0037-1106
    Electronic ISSN: 1943-3573
    Topics: Geosciences , Physics
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  • 20
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