ISSN:
0268-2605
Keywords:
Organometallics
;
trimethylaluminum
;
photodissociation
;
time-of-flight mass spectrometry
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Photodissociation of trimethylaluminum [Al(CH3)3] adsorbed on a silica (SiO2) substrate at 110 K has been studied by multiphoton ionization time-of-flight mass spectrometry. Translational energy distributions of aluminum and AlCH3 fragments can be fitted with a composition of two Maxwell-Boltzmann distributions. The two components are attributed to different environments of photodissociating parent molecules in the multilayer.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590070503
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