ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The disproportionation and combination reactions between CF2H and C2H5 radicals have been studied in the gas phase from room temperature to 70°C. For the pathway which yields CF2H2 + C2H4, relative to CF2HC2H5, Δ = 0.072 ± 0.019. The competing reaction channel that produces CF2 + C2H6 is approximately four times as efficient, with Δ = 0.265 ± 0.038. With CF2D radicals an isotope effect for the CF2 + C2H5D reaction pathway was observed with Δ ≅ 0.2.
Additional Material:
7 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550140310
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