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Precise measurement of the J=2←1 fine structure interval in N(II) by far-infrared laser magnetic resonance (1986)

Cooksy, A. L. ; Hovde, D. C. ; Saykally, R. J.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 84 (1986), S. 6101-6107

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Far-infrared laser magnetic resonance spectroscopy has been used to measure the J=2←1 fine structure intervals in the 3P ground states of singly ionized 14N and 15N atoms. In 14N(II) this separation is 2459.3703(14) GHz, and in 15N(II) it is 2459.3816(19) GHz. The hyperfine constants and gJ factors have been evaluated for both isotopes. Zero field energies for the hyperfine components of the J=2←1 transition in both isotopes are given in an effort to facilitate their observation in interstellar sources. A complete description of the hyperfine and Zeeman Hamiltonian matrix elements for atomic fine structure transitions is given in an LS coupled basis set.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.450800

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