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Mass spectra of Ca–O and Ba–O clusters (1989)

Martin, T. P. ; Bergmann, T.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 90 (1989), S. 6664-6667

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Mass spectra of metal-rich, singly and doubly ionized BanOx clusters are characterized by high peak intensities for n=13, 19, 23, 26, 29, 32, and 35 independent of the number of oxygen atoms (x=1,2,3,4). These values are identical to the magic numbers found for Ar clusters. The mass spectra of CanO show a similar behavior. Mass spectra of stoichiometric, doubly ionized [Ca(CaO)n]++ clusters are characterized by low peak intensities for n=14, 24, 32, 38, 40, 50, and 64. These values correspond to unstable clusters formed by the addition of one Ca atom or one CaO molecule to a closed rectangular block of atoms with rock salt structure.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.456285

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