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Spectra in the chaotic region: A classical analysis for the sodium trimer (1989)

Gomez Llorente, Jose M. ; Taylor, Howard S.

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 91 (1989), S. 953-962

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: Classical mechanics is used to compute the low resolution spectrum of Na3 in the chaotic regime. The regularity in the spectrum is shown to be due to a family of C2v symmetry tori involving a high amplitude breathing mode and a high amplitude bending mode. These tori are the two mode survivors of the three mode tori whose quantization gives the four assignable lower energy vibrational levels.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.457147

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