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A Dimeric Copper(II) Complex of an α-Hydroxylated Acid: [Cu(C14H8O3)(C9H7N)(H2O)]2.2C3H7NO.2H2O (1996)

Yu, Y. P. ; Zhu, D. L. ; Liu, S. X.

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 52 (1996), S. 628-630

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The structure of bis[μ-(9-hydroxy-1:2κ2O)-9-fluorenecarboxylato(2-)]-1κO; 2κO-bis[aqua(quinoline-κN)copper(II)] bis(dimethylformamide) dihydrate has been determined by single-crystal X-ray diffraction. The binuclear CuII unit comprises a pair of Cu atoms linked by two hydroxyl O-atom bridges. The coordination polyhedron around each Cu atom is a distorted square pyramid, the basal plane consisting of one N atom from the quinoline ligand, one carboxyl O atom and two bridging O atoms from two α-hydroxylated acid ligands, while the axial coordination site is occupied by an O atom of the coordinated water molecule with a Cu—O bond length of 2.424 (4) Å.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270195011474

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