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Solid-solid reactions, II: Mechanism of barium metatitanate synthesis (1979)

Cournil, Michel ; Soustelle, Michel ; Thomas, Gérard

Springer

Oxidation of metals 13 (1979), S. 89-104

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ISSN: 1573-4889

Keywords: BaTiO3 ; kinetics ; solid state ; mechanisms

Source: Springer Online Journal Archives 1860-2000

Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Abstract The authors propose a mechanism for the solid-solid reaction BaCO3+ TiO2→BaTiO3+CO2. This mechanism is based on the real structure of the present semiconductors. The reactions at different interfaces and the diffusing species are identified. The reaction rates are calculated and the dependence of the reaction rate upon O2, N2, and CO2 gas pressure is interpreted and discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00715872

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