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The effects of aqueous solvent structure on the mutarotation kinetics of glucose (1977)

Livingstone, G. ; Franks, F. ; Aspinall, L. J.

Springer

Journal of solution chemistry 6 (1977), S. 203-216

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ISSN: 1572-8927

Keywords: Glucose ; kinetics ; mixed solvent ; kinetic isotope effect ; enthalpy of activation ; entropy of activation ; tetrahydrofuran ; tert-butanol ; mutarotation

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The mutarotation rates of glucose in aqueous mixtures of tetrahydrofuran andtert-butanol in the mole fraction (xi) range 0〈xi〈0.2 have been measured at 5° intervals in the range 5–35°C. The kinetic deuterium isotope effects have been determined for the same solvent compositions at 25 and 35°C. A statistical analysis of the Arrhenius plots indicates that the experimental errors, although small, are too large for the establishment of any compensation behavior between ΔH

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00646739

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