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Salting coefficients for gases in seawater from scaled-particle theory (1975)

Masterton, William L.

Springer

Journal of solution chemistry 4 (1975), S. 523-534

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ISSN: 1572-8927

Keywords: Salting coefficient ; scaled-particle theory ; gas solubilities ; seawater ; helium ; neon ; argon ; oxygen ; nitrogen

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Experimental values of the salting coefficients for He, Ne, Ar, O2, and N2 in seawater are compared with values calculated from scaled-particle theory. The agreement is reasonably good; the average difference between calculated and observed values at 25°C is 0.007. Scaled-particle theory predicts correctly thatk s should decrease as the temperature increases and that this effect should be most pronounced at low temperatures. However, the predicted magnitude ofdK s/dt is only about half of that observed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00650690

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