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Die katalytische Wirkung von Metallionen auf die Stabilität von Phosphagenen (1963)

Clark, V. M. ; Warren, S. G.

Springer

Cellular and molecular life sciences 19 (1963), S. 514-515

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ISSN: 1420-9071

Source: Springer Online Journal Archives 1860-2000

Topics: Biology , Medicine

Notes: Summary Phosphoroguanidates, a class of compounds which includes the enzymatically-active phosphagens, exhibit exceptionalin vitro stability. This lack of reactivity implies anin vivo mode of activation, as yet undiscerned. A variety of metal ions catalyse the cleavage of the phosphorus-nitrogen bond with consequent phosphoryl-group transfer, but the enhancement of rate seems insufficient to account for the known activities of phosphoro-creatine and phosphoro-arginine. It is suggested that yet another mode of activation, chemical or biochemical, awaits discovery.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02150883

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