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Anionic polymerization with expansion in volume (1987)

Brady, Robert F. ; Simon, Frederick E.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 231-239

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ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: New bicyclic and tricyclic compounds have been synthesized by the Lewis acid-catalyzed condensation of epoxides with cyclic acid anhydrides or cyclic bislactones. These materials take part in the anionic addition polymerization of amine-functional polyamides with diepoxides, and modify the shrinkage that is characteristic of the reaction. It is possible to control the extent of shrinkage by choosing an appropriate comonomer and by adjusting the concentration of this material in the reaction mixture.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1987.080250120

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