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Stabilization at high temperatures (1980)

Brun, E. B. ; Shustova, O. A. ; Kuchanov, S. I. ; [et al.]

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 2461-2470

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A general detailed model of polymer oxidative degradation in the presence of a stabilizer-oxygen acceptor was considered. The motion of the degradation zone boundary and the sample lifetime were obtained for various conditions of the process. In particular, it is shown that within the given concentration immobile oxygen acceptor has the best stabilizing properties. The theoretical results are compared with the experimental data obtained by using two independent methods: polymer sample cracking and a change in the ESR signal. Good agreement between theory and experiment was obtained.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1980.170180805

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