ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
We have investigated solvent effects on the aromatic electrophilic substitution reaction of m-fluorophenyltriethyltin, 1, with mercuric chloride in order to obtain information about the polarity of the transition state. Second-order rate constants have been determined for the reaction of 1 with mercuric chloride in methanol and methanol-water mixtures at 25·0°C, allowing determination of δΔG
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610061006