ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The stoichiometry of the reaction of TIIII with ascorbic acid (H2A) in the presence and absence of chloride ion conforms to TIIII + H2A 〉 TII + 2H+ + A. where A is dehydroascorbic acid. The reaction exhibits complex kinetics and the reactivity of various chlorothallium (III) species decreases in the order of [TIOH]2+ 〉 TI3+ 〉 [TICI]2+ 〉 [TICI2]+ 〉 TICI3 〉 [TICI4]-. The mass balance relationship was employed to calculate the equilibrium concentration of the chloride ion for evaluation of the rate constants.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610060309