ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Using single crystal data the occurence of the K2NaCrF6 type of structure for Cs2NaInF6 (a = 8.905 Å) has been confirmed and xF determined to be xF = 0.229; in consequence: In-F = 2.039 Å [430 (hkl) with h + k = 2n and h = 0 to 7; R = 11.1%; Mo—Kα.]. The Madelung Part of Lattice Energy is calculated and discussed in detail.
Notes:
An Einkristallen von Cs2NaInF6 (a = 8,905 Å) wurde xF mit Fourier- und least squares-Methoden zu xF = 0,229, also In-F = 2,039 Å bestimmt. Dass Vorliegen des K2NaCrF6-Typs wurde bestätigt [430 Reflexe (hkl) mit + k = 2n und h = 0 bis 7; R = 11,1%; Mo—Kα.w]. Der Madelung-Anteil der Gitterenergie wird berechnet und diskutiert.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19703760310
