ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The proportion of difunctional and monofunctional products with the original carbon skeleton was determined in the oxidates of n-decane, n-tridecane, n-pentadecane, and n-octadecane to about 0.32. This proportion does not significantly depend on the conversion of the starting paraffin. As well as mono- and difunctional products with the original carbon skeleton already at very low conversions of n-tridecane, about 45% of lower oxygen-containing compounds, for example aldehydes, alkan-2-ones, carboxylic acids and γ-lactones, are also obtained. Obviously, a part of the difunctional primary products reacts very fast with scission of the carbon chain, forming lower oxygen-containing compounds.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19873290402
