ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Photocatalytical Systems. LXIV. Theoretical Investigations of the Charge Transfer and of the Photochemical Reactivity of d6 Transition Metal Complexes with π Acceptor LigandsQuantum chemical investigations concerning the charge transfer interactions between a d6 complex fragment and heterocyclic nitrogen ligands are reported. The influence of inductive, mesomeric and steric effects on the π acceptor ability of the isolated ligand and on the electronic structure of the pentacyano-ferrate(II) mixed ligand compounds has been investigated and possibilities to sensitize spectrally the Fe(CN)5L3- system (L= pyridine-type ligand) with regard to their photochemical reactivity are discussed.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19843260615