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Formation of the First Trimeric Monoterpenoid Indole Alkaloids (1989)

Schübel, Helmut ; Fahn, Walter ; Stöckigt, Joachim

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 72 (1989), S. 147-150

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Under O2, the Aspidosperma alkaloid tabersonine (1) was converted by a crude enzyme preparation from leaves of mature plants of Catharanthus roseus G DON into the trimeric 3-hydroxy-14′-(3α″-tabersonyl)voafrine B (4) which was easily reduced by NaBH4 to 14′-(3α″-tabersonyl)voafrine B ( = tertabersonine; 5). Compounds such as 4 and 5 are the first trimeric alkaloids in the series of monoterpenoid indole alkaloids.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19890720119

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