ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The crystal structure of the complex [phen · phen · phen] · NaBr · 2 CHCl3 of the macrobicyclic ligand 1 has been determined. The complex is of cryptate type, the Na+ cation being contained in the molecular cavity of 1 and coordinated to all eight N-atoms. The ligand has a propeller shape and interconverts in solution between the two enantiomeric helical forms.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19850680609