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On the Nature of the 7-Norbornadienyllithiums. Preliminary Communication (1984)

Goldstein, Melvin J. ; Wenzel, Timothy T.

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 67 (1984), S. 2029-2036

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Lithium reductions of 7-chloronorbornadiene and of bis(7-norbornadienyl)mercury both provide (C7H7)2Li2 (5a). This product is accompanied by C7H7Li2Cl (5c) in the first case, and by C7H7Li (5b) in the second. The theoretically anticipated properties of all three organolithiums are apparent in the consistent Cs symmetry of their hydrocarbon ligands, their protolytic destruction by 12-crown-4, and their significant J(C(7), Li) (5a, 7.6; 5b, 16.0; 5c 8.9 Hz).

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19840670802

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