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Reactivity of amines toward tert-butoxy radicals: Effect of solvent and amine structure (1981)

Encina, M. V. ; Díaz, S. ; Lissi, E.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 13 (1981), S. 119-123

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The reactivity of amines towards tert-butoxy radicals depends upon the amine ionization potential and the solvent, indicating that polar structures contribute to the reactivity of these compounds. Nevertheless, the dependence with the amine potential is smaller than the one obtained for the quenching of carbonyl excited states by amines and other factors as the strength of the broken hydrogen bond and steric hindrance are also significant in determining the rate of the process.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550130203

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