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Abstraction by hydrogen atoms from ethylene, propylene, butene-1, and cis- and trans-butene-2 (1972)

Falconer, W. E. ; Sunder, W. A.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 4 (1972), S. 315-324

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The position of abstraction by H atoms from ethylene, propylene, butene-1, and cis- and trans-butene-2 and the rates of abstraction relative to addition have been measured at 25°C. Only allylic abstraction was observed. From ethylene, abstraction relative to addition was ≤3×10-4. For propylene, butene-1, cis-butene-2, and trans-butene-2, abstraction occurred on 0.2%, 1.6%, 1.5%, and 0.9% of the reactive encounters, if dis-proprotionation-combination ratios for allyl and alkyl radicals are similar to those for alkyl-alkyl pairs.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550040308

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