ISSN:
0009-2940
Keywords:
Rhenium
;
Technetium
;
Radiop[pharmaceuticals
;
Mixed-ligand complexes
;
sulfur
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CH2]2SR)], × = Cl, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2]2SR, R =nBu, Et, Bz) dissolved in glacial acetic acid to give octahedral complexes of the type [ReOCl3(RS[CH2]2SR)] (1a-c). In concentrated hydrobromic acid, nBu-S(Ch2)2S-nBu leads to the corresponding tribromo complexes (2). The X-ray structure of shows a distorted octahedron with facial coordination of the bromide ligands. The sulfur atoms are cis coordinated to the terminal oxygen. Dissolution o f1a (R = nBu) in methanol leads to the substitution of the chloride trans to the oxo ligand by a meth oxy group. The resultant complex [ReOCl2(MeO) (nBu-S[CHL2]2S-nBu)] (3) is stable and can be isolated from methanolic solution, but changes to the μ-oxo-bridged dirhenium complex μ-oxobis[dichloro(5,6-dithiadidodecane)oxorhenium(V)] (4) when dissolved in other organic solvents. 1a reacts with an excess of benzenethiol by substitution of two chlorides to give the mixed-ligand complex bis(benzenethiolate)chloro(5,8-dithiadodecane)oxorhenium(V) (5a). The related 4-methylbenzenethiolato complex 5b was synthesized starting from the μ-oxo complex 4. X-ray crystal structure determination of 5b shows the equatorial arrangement of the sulfur atoms. The trans position to the oxygen atom is occupied by a chloride ion.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971300927
