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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 115 (1982), S. 3049-3062 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transition Metal Fulvene Complexes, XX. Carbonyl Metal Complexes with Dimeric Fulvene LigandsThe synthesis and structure of four complexes (3a, 7, 9, 10) with dimeric fulvene ligands are reported. The compounds are formed in low yields by reaction of unsubstituted fulvene with Fe2(CO)9 (3a), of 6,6-diethylfulvene with Fe2(CO)9 (7), and of 6,6-bis(methylthio)fulvene with (CH3CN)3Mo(CO)3 (9 and 10), respectively. Moreover the structure of dimeric dimethylfulvene (11) has been determined by X-ray diffraction.
    Notes: Es wird über die Synthese und Struktur von vier Komplexen (3a, 7, 9, 10) mit dimeren Fulvenliganden berichtet. Die Verbindungen entstehen in geringer Ausbeute bei der Reaktion von unsubstituiertem Fulven mit Fe2(CO)9 (3a), von 6,6-Diethylfulven mit Fe2(CO)9 (7) bzw. von 6,6-Bis(methylthio)fulven mit (CH3CN)3Mo(CO)3 (9 und 10). Zusätzlich wurde die Struktur des dimeren Dimethylfulvens (11) röntgenographisch bestimmt.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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