ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Contributions to the Chemistry of Boron, CV. (N-Lithiomethylamino)dimethylborane as a Reagent for the Preparation of N-Functional AminodimethylboranesThe reagent (CH3)2 — N(CH3)Li (1) allows the synthesis of many borylaminoelement compounds such as (CH3)2B — NCH3 — BCH3 — N(CH3)2, (CH3)2Si[NCH3 — B(CH3)2]2, (CH3)2B - NCH3 — Si(CH3)2 — NCH3 — Si(CH3)2Br, (CH3)2B — NCH3 — P(CH3)2 or (CH3)2B — NCH3 — As(CH3)2. Multifunctional element halides cause the formation of a complex mixture of products, and this is in part due to cyclocondensation reactions of longer chain compounds.
Notes:
Das Reagens (CH3)2B — N(CH3)Li (1) ermöglicht die Synthese zahlreicher Borylaminoelement-Verbindungen wie (CH3)2B — NCH3 — BCH3 — N(CH3)2, (CH3)2Si[NCH3 — B(CH3)2]2, (CH3)2B — NCH3 — Si(CH3)2 — NCH3 — Si(CH3)2Br, (CH3)2B — NCH3 — P(CH3)2 oder (CH3)2B — NCH3 — As(CH3)2. Mit mehrfunktionellen Elementhalogeniden wird die Produktpalette komplexer, was auch auf Cyclokondensation der längerkettigen Verbindungen zurückzuführen ist.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19801130230
