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Chemie der Amino-oxime, IV. Die Umsetzung von syn-α-Amino-ketoximen mit Aldehyden (1970)

Gnichtel, Horst

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 103 (1970), S. 3442-3447

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: The Chemistry of Amino Oximes, IV. The Reaction of syn-α-Aminoketoximes with Aldehydessyn-ω-Aminoacetophenonoximes react with acetaldehyde to form 5.6-dihydro-4H-1.2.5-oxadiazines, the structure of which was determined by spectroscopic methods. With benzaldehyde azomethines are formed, which isomerise to syn-ω-(benzylimino)acetophenonoximes.

Notes: syn-ω-Amino-acetophenonoxime bilden mit Acetaldehyd 5.6-Dihydro-4H-1.2.5-oxadiazine. Die Struktur wurde durch spektroskopische Untersuchungen bestimmt. Mit Benzaldehyd entstehen die Azomethine, die sich zu syn-ω-Benzylimino-acetophenonoximen isomerisieren.

Additional Material: 6 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19701031110

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