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Thermodynamic properties of strong electrolytes in aqueous solutions (1973)

Bromley, Leroy A.

Hoboken, NJ : Wiley-Blackwell

AIChE Journal 19 (1973), S. 313-320

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ISSN: 0001-1541

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: A generalized analytic correlation is presented for activity coefficient. osmotic coefficient, enthalpy, and heat capacity of single and multicomponent strong aqueous solutions. A good correlation for each salt to an ionic strength of six is obtained by assigning a single parameter “B” value to each salt. These B values are well approximated by assigning two parameters for each ion. Values presented for the common ions at 25°C allow the estimation of activity and osmotic coefficients of many unmeasured salt solutions.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/aic.690190216

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