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Ionization and dissociation of diethylamine by field ionization mass spectrometry (1983)

Zahran, N. F. ; Helal, A. I.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 18 (1983), S. 212-214

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The field ionization mass spectrum of diethylamine on a 5 μm activated wire at 300 K yields surface product ions like protonated molecular ions and doubly charged ions as well as gas phase ions like parent minus CH3 group. Variations of the reaction rate as a function of the decomposition times in the range 10-11-10-6 s for the elimination of a CH3 group are studied. The reaction rates are evaluated with the help of the retarding potential technique.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210180507

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