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Energy partitioning in the metastable fragmentation [C3H7]+ → [C3H5]+ + H2 (1978)

Holmes, John L. ; Osborne, Alexander D.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 13 (1978), S. 133-134

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The dish-topped metastable peak for the fragmentation [C3H7]+ → [allyl]+ + H2 is generated by the threshold fragmentation. The fraction of the reverse activation energy which is partitioned as translational energy of the products is 0.9 ± 0.1. It is proposed that a similar partitioning coefficient applies to the excess internal energy above threshold.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210130304

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