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Negative ion mass spectra of highly fluorinated compounds (1969)

Chait, E. M. ; Askew, W. B. ; Matthews, C. B.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 2 (1969), S. 1135-1140

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The negative ion mass spectra of highly fluorinated molecules with varying functionality are discussed. Attempts to obtain negative molecular ions where no positive molecular ion was observed met with little success. An interesting structural correlation for fluorinated ethers was developed based upon the observation of the abundant perfluoro alkoxide anions, CF3O- and CF3(CF2)2O-, in the negative ion mass spectrum.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210021110

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