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Mass spectral correlations for some fluorinated alkanes (1968)

McCarthy, E. R.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 1 (1968), S. 81-86

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The cracking patterns of thirty-three fluorinated methanes, ethanes and propanes have been tabulated. For many of the compounds molecular ions were not observed. A comparison has been made of some of the halomethyl ion abundances with stabilization energies that have recently been derived from appearance potential measurements. Rearranged halomethyl ions occur frequently in the fluoroethane spectra. Their intensities often exceed those resulting from simple carbon bond rupture.

Additional Material: 5 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210010109

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