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The conformation of meso and racemic 2,3,4-trichloropentanes - model compounds for polymers derived from 1,2-dichloroethylenes (1972)

Clifford, R. P. ; Ewing, D. F.

Chichester : Wiley-Blackwell

Organic Magnetic Resonance 4 (1972), S. 473-480

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ISSN: 0030-4921

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: On the basis of coupling constants and chemical shifts the conformation of meso and racemic 2,3,4-trichloropentanes have been determined. The meso isomer exists as an equilibrium between the expected rotameric forms but the racemic isomer is anomalous and exists almost entirely as a distorted form of a rotamer which has parallel 1:3 interactions. The significance of these conformations is discussed in relation to the likely conformation and stability of the corresponding stereoregular polymers, which may be derived from cis- and trans-1, 2-dichloroethylene.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/mrc.1270040407

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