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The mass spectral fragmentation of 9α-hydroxy steroids and related compounds (1977)

Horváth, Gyula ; Ambrus, Gábor

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 4 (1977), S. 376-380

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ISSN: 1052-9306

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The fragmentation processes occurring in various 9α-hydroxy steroids upon electron have been studied. The mechanisms proposed for the formation of the prominent ions in these spectra have been confirmed with the aid of deuterium labelling, measurements on metastable ion decompositions, low eV spectra and high resolution mass measurements. The fragmentation of the corresponding 9-oxo-9,10 seco steroids, which shows analogy to that of the 9α-hydroxy compounds in many respects, has also been discussed.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/bms.1200040610

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