ISSN:
0306-042X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Field desorption (FD) mass spectra of alkali metal salts of organic acids are characterized by fluctuating ion current, high anode temperature, high abundance of metal ions and low abundance of structurally significant organic ions. As part of a continuing study of matrix effects on the FD process, we have now found that addition of pentaerythritol or cis-inositol results in a smoother desorption and a marked enhancement of intensity in a variety of such spectra. Results are presented for 12-hydroxystearic acid sodium salt; anthraquinone-2-sulfonic acid sodium salt.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/bms.1200090206