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    Call number: AWI G3-19-92414
    Description / Table of Contents: Permafrost, defined as ground that remains frozen for at least two consecutive years, is a prominent feature of polar regions. In the Northern Hemisphere, approximately 23 million km2 of the ground are affected by permafrost. Climatic warming, which has a greater effect on the Arctic than on any other region on Earth, leads to permafrost thaw, caused by gradual deepening of the seasonal unfrozen layer (active layer), thermokarst formation (i.e. land subsidence due to ground ice loss) and thermo-erosion. In the course of thaw, formerly freeze-locked organic carbon (OC) is mobilized and mineralized into greenhouse gases (GHGs), fostering further climate warming – a process known as permafrost carbon feedback. Current climate models focus on GHG release from gradual deepening of the active layer and neglect the OC turnover during lateral transport induced by thermokarst and abrupt thermo-erosion. As such, the accelerated erosion of Arctic permafrost coasts, which make up ~34 % of the global coasts, deliver vast amounts of OC into the Arctic Ocean. However, little is known about the amounts of labile and fast bioavailable dissolved OC (DOC), the impact of thermokarst on mobilized organic matter (OM) characteristics, and the release of GHGs from eroding permafrost coasts. To fill that knowledge gap, the main objectives of the thesis are to investigate (i) how much DOC is mobilized from coastal erosion, (ii) how thermokarst and -erosion alters OM characteristics upon thaw on transit to the ocean, and (iii) how much GHGs are emitted from the nearshore zones of eroding permafrost coasts. Field work and sampling took place along the Yukon coast and on Qikiqtaruk (Herschel Island) in the western Canadian Arctic. An interdisciplinary approach was used to quantify OM (OC and nitrogen) as well as to identify degradation processes. The methods used included sedimentology, geo- and hydrochemistry, remote sensing, statistical analyses, and gas chromatography. The thesis shows that considerable amounts of DOC are released from eroding permafrost coasts. Although OC fluxes into the ocean are dominated by DOC from Arctic rivers and particulate OC (POC), labile DOC derived from permafrost plays an important role as it is quickly available for biogeochemical cycling and turnover into GHGs. During transit from land to ocean OM characteristics are substantially altered by thermokarst formation and thermo-erosion. In mudpools, originating from in-situ thawed permafrost, as well as in thaw streams draining thermokarst features towards the ocean, mobilized OM issubject to dilution with melted ground ice and degradation, which result in a decrease of OM contents by more than 50 %. The turnover of OC continues in the nearshore zone. The biochemically most labile OC portions are rapidly lost within months and mineralized into GHGs. The production of GHGs in the ocean is 60 to 80 % as efficient as on land and primarily in form of carbon dioxide (CO2), due to aerobic conditions in the nearshore zone. During each open water season in the Arctic approximately 0.7 to 1.2 Tg of CO2 are emitted from the coastal fringe. The remaining OM is buried in nearshore and shelf sediments, potentially remobilized by waves, currents and ice scouring at later stages. To conclude, the thesis shows that eroding permafrost coasts release large amounts of OC, from which considerable portions are labile DOC. In the course of thermokarst formation and thermo-erosion, OM is diluted and the most labile portions subject to rapid turnover into GHGs. This shows that eroding permafrost coasts are a major yet neglected source of CO2 to the atmosphere. With increasing temperatures and longer sea ice-free conditions projected for the Arctic, the erosion of permafrost coasts accelerates. Consequently, the transfer of OC to the ocean accompanied by GHG production increases, which is expected to have drastic impacts for the climate and coastal ecosystems.
    Type of Medium: Dissertations
    Pages: IX, 106, A1-A-57 Seiten , Illustrationen, Diagramme
    Language: English
    Note: Table of contents Abstract Zusammenfassung Abbreviations and nomenclatureI 1. Introduction 1.1 Scientific background 1.1.1 Permafrost and ground ice 1.1.2 Organic carbon pools and fluxes into the Arctic Ocean 1.1.3 Climate warming and permafrost thaw 1.1.4 Permafrost degradation and coastal erosion 1.1.5 Study area Yukon coast and Qikiqtaruk 1.2 Knowledge gaps 1.3 Aims and objectives 1.4 Thesis structure and author's contribution 2. Eroding permafrost coasts release low amounts of dissolved organic carbon (DOC) from ground ice into the nearshore zone of the Arctic Ocean 2.1 Abstract 2.2 Introduction 2.3 Study area 2.4 Methods 2.4.1 Field work 2.4.2 DOC concentration 2.4.3 DOC flux estimation 2.5 Results 2.5.1 Segmentation of the coast - literature synthesis 2.5.2 DOC concentration 2.5.3 DOC stocks and fluxes 2.6 Discussion 2.6.1 DOC concentrations in ground ice 2.6.2 DOC fluxes from the YC 2.6.3 DOC fluxes and the Arctic carbon budget 2.7 Conclusion and Outlook 2.8 Acknowledgements 3.Transformation of terrestrial organic matter along thermokarst-affected permafrost coasts in the Arctic 3.1 Abstract 3.2 Introduction 3.3 Study area 3.3 Methods 3.3.1 Field work 3.3.2 Sedimentology, stratigraphy, and vegetation 3.3.3 Organic matter 3.3.4 Statistics 3.3.5 Transformation of organic matter 3.3.6 Fate of organic matter in the nearshore zone 3.4 Results 3.4.1 Sedimentology, stratigraphy, and vegetation 3.4.2 Organic matter 3.4.3 C/N-ratios and δ13C 3.4.4 Biomarkers 3.5 Discussion 3.5.1 Transformation of organic matter in the disturbed zone 3.5.2 Fate of organic matter in the nearshore zone 3.5.3 Environmental impact of the RTS 3.6 Conclusion 3.7 Acknowledgements 4. Rapid greenhouse gas release from eroding permafrost coasts 4.1 Summary 4.2 Background 4.3 Study site 4.4 Sampling and incubation setup 4.5 Findings and discussion 4.6 Conclusion 4.7 Methods 4.7.1 Incubation conditions 4.7.2 Gas measurements 4.7.3 Geo- and hydrochemical analysis 4.8 Acknowledgements 5. Synthesis 5.1 Mobilization of permafrost OC pools by coastal erosion 5.2 Transformation of permafrost OM on transit from land to sea 5.3 Fate and pathways of permafrost OC in the nearshore zone 5.4 Conclusion and outlook References Appendix I: Dissolved organic carbon (DOC) in Arctic ground ice I-1 Abstract I-2 Introduction I-3 Study area and study sites I-4 Material and methods I-4-1 Laboratory analyses I-4-2 Statistical methods I-5 Results I-5-1 DOC and DIC concentrations I-5-2 Correlation matrix I-5-3 Principal components I-5-4 Univariate Tree Model (UTM) I-6 Discussion I-6-1 DOC stocks in ground ice and relevance to carbon cycling I-6-2 Carbon sequestration and origin in relation to inorganic geochemistry I-6-3 DOC mobility and quality upon permafrost degradation I-7 Conclusions and outlook I-8 Acknowledgements Appendix II: Supplementary material for Chapter 2 II-1 Supplementary table - Ground ice and geochemical data II-2 Supplementary table - Coastal segments and DOC flux Appendix III: Supplementary material for Chapter 3 III-1 Normalized Differenced Vegetation Index map III-2 Photograph of a massive ice bed in a RTS III-3 Calculation of biomarker proxies III-4 Supplementary table - Summary of geochemical data III-5 Supplementary table - Summary of statistical analysis AppendixI V: Supplementary material for Chapter 4 IV-1 Design of the incubation experiment IV-2 Photograph of a standard incubation setup IV-3 Conversion of gas amounts into mass IV-4 Total and daily aerobic CH4 production IV-5 Histogram summarizing OC losses and CO2 emissions IV-6 Supplementary table - Summary of TOC, DOC, and pH data IV-7 Supplementary table - Summary of TN, TOC/TN, and δ13C-TOC data IV-8 Supplementary table - Summary of total CO2 and CH4 production data IV-9 Supplementary table - Comparison of incubation setups IV-10 Supplementary table - Summary of daily CO2 production data IV-11 Supplementary table - Summary of daily CH4 production data Acknowledgements-Danksagung
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