ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title complex, [Fe(C32H36N4)(C4H8O)2]ClO4, shows an S4-ruffled porphyrin ring, where the maximum deviation of the meso-carbon from the least-squares plane of the [Fe(C20N4)] core is as high as 0.675 (9) Å. This is the highest class of deviation among S4-ruffled iron(III) porphyrin complexes. The average Fe—Np bond distance is 1.967 (12) Å (Np denotes an N atom of the equatorial ligand).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100015833