ISSN:
1572-8838
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Electrical Engineering, Measurement and Control Technology
Notes:
Abstract Modulation and photon counting Raman spectroelectrochemical methods have been applied for studying amorphous carbon electrode surfaces during the electrolysis of HgCl2 in LiCl−KCl eutectic at 370°C. A new Raman band measured at 152 cm−1 was attributed to subvalent Hg2Cl2 species. The Raman signal arises from the melt solvent having appreciable Hg2Cl2 concentrations in the vicinity of the cathode.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01024091