ISSN:
0032-3888
Schlagwort(e):
Chemistry
;
Chemical Engineering
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Maschinenbau
,
Physik
Notizen:
Differential thermal analysis offers a convenient and rapid way of determining stabilization levels in polyolefin compositions. Since it is normally used at temperatures in the fabrication range, it provides a direct readout of processing stability. At the same time, because the chemistry of the polymer system at these temperatures may be quite different from that at normal use temperatures, judgment must be exercised in attempting to extrapolate high temperature data. New factors can come in at either end of the temperature range which are inoperative at the other extreme.The experimental procedures used are described, and the special precautions necessary for operation down to the 140-150°C range indicated. Problems arising from sample inhomogeneities are discussed, and the critical importance of stabilizer migration in the solid state pointed out, including invalidation of extrapolation down to normal temperatures of data taken above the melting range.
Zusätzliches Material:
7 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pen.760130606
