ISSN:
0749-1581
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The out-of-cage CIDNP effects, and kinetics of the out-of-cage reactions between the methyl radicals and the other radicals produced from the donor admixtures have been studied during the thermal decomposition of di-t-butylperoxalate (DTBPO). The DTBPO decomposition proves to be a good source of methyl radicals.The CIDNP effects on the methyl protons and on the nuclei of the other alkyl radicals are determined both by the out-of-cage radical collisions and the kinetics of out-of-cage recombination.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260051108