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Synthesis and NMR study of 5-furylmethylenehydantoins and 5-thienylmethylenehydantoins (1991)

Tan, Sau-Fun ; How, Gee-Fung ; Yeoh, Phee-Teik

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 4 (1991), S. 681-688

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Two series of 5-furylmethylenehydantoins and 5-thienylmethylenehydantoins were prepared and their 1H and 13C NMR spectra studied in comparison with those of compounds in the analogous 5-aryl- and 5-pyridyl- series. Differences in the effects of the aromatic, six- or five-membered heteroaromatic rings are discussed. Spectral analysis enables Z/E configurations to be assigned with confidence and conformational preferences to be qualitatively deduced. Some interesting solvent effects were also observed.

Additional Material: 5 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610041106

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