ALBERT

Description: Present day system Earth research utilizes the tool ‘Scientific Drilling’ to access samples and to monitor deep Earth processes that cannot be tackled by other scientific means. Unlike most laboratory experiments or computer modelling, drilling projects are massive field endeavours requiring intense collaboration of researchers with engineers and service providers. In the framework of the International Continental Scientific Drilling Program, ICDP, more than seventy drilling projects have been conducted, from multiyear big research programs to short, smallscale deployments such as lake drilling projects. ICDP has supported these projects not only through grants covering field-related costs, but also through a variety of scientific-technical services and support, as well as active help in data management, outreach and publication. These services are described in this booklet. Due to its instructional character, we call it the ICDP Primer.

Description: Highlights • Development of an autonomous DIC analyzer based on Conductometric technique using a cell with 4 hollow brass electrodes. • CO2 extraction from seawater using a gas diffusion cell with a “Tube In A Tube” configuration and a gas permeable membrane. • Formulation of mathematical temperature and salinity correction to determine accurate DIC concentration. • Demonstration of the analyzer performance in the southwest Baltic Sea. Abstract Background The increase in anthropogenic CO2 concentrations in the Earth's atmosphere since the industrial revolution has resulted in an increased uptake of CO2 by the oceans, leading to ocean acidification. Dissolved Inorganic Carbon (DIC) is one of the key variables to characterize the seawater carbonate system. High quality DIC observations at a high spatial-temporal resolution is required to improve our understanding of the marine carbonate system. To meet the requirements, autonomous DIC analyzers are needed which offer a high sampling frequency, are cost-effective and have a low reagent and power consumption. Results We present the development and validation of a novel analyzer for autonomous measurements of DIC in seawater using conductometric detection. The analyzer employs a gas diffusion sequential injection approach in a “Tube In A Tube” configuration that facilitates diffusion of gaseous CO2 from an acidified sample through a gas permeable membrane into a stream of an alkaline solution. The change in conductivity in the alkaline medium is proportional to the DIC concentration of the sample and is measured using a detection cell constructed of 4 hollow brass electrodes. Physical and chemical optimizations of the analyzer yielded a sampling frequency of 4 samples h−1 using sub mL reagent volumes for each measurement. Temperature and salinity effects on DIC measurements were mathematically corrected to increase accuracy. Analytical precision of ±4.9 μmol kg−1 and ±9.7 μmol kg−1 were achieved from measurements of a DIC reference material in the laboratory and during a field deployment in the southwest Baltic Sea, respectively. Significance This study describes a simple, cost-effective, autonomous, on-site benchtop DIC analyzer capable of measuring DIC in seawater at a high temporal resolution as a step towards an underwater DIC sensor. The analyzer is able to measure a wide range of DIC concentrations in both fresh and marine waters. The achieved accuracy and precision offer an excellent opportunity to employ the analyzer for ocean acidification studies and CO2 leakage detection in the context of Carbon Capture and Storage operations.

Description: Geochemical study of volcaniclastic material and radiocarbon dating of charred plant debris from Holocene deposits of the Guram site, which is located in vicinity of Vetrovoi Isthmus on Iturup Island, demonstrate that an explosive eruption (VEI 4-5) occurred there about 2000 years ago. The geochemical and age similarity with the tephra of marker layer CKr that was distinguished on Iturup, Urup, Simushir, Rasshua, and Matua islands of the Kuril Island Arc led to the conclusion that this eruption is possibly a source of this tephra. The data presented are proposed as a motivation for revision of the volcanic hazard on Iturup Island.

Description: The genome sequence of the moderately halophilic Lamprobacter modestohalophilus ShNLb02 was compared to those of other Lamprobacter and Halochromatium species. It revealed an average nucleotide identity of 94% to Lpb. modestohalophilus DSM 25653 and of 89.7% to Halochromatium roseum DSM 18859, underscoring their close phylogenetic relationship.

Description: Der Biodiversitätsverlust schreitet in bedrohlichem Ausmaß voran. Mit dem Global Biodiversity Framework und voraussichtlich dem Nature Restoration Law bestehen nun auf internationaler und europäischer Ebene vielversprechende Ansätze, ihm Herr zu werden. Jetzt ist der Bundesgesetzgeber – nicht zuletzt aus verfassungsrechtlichen Erwägungen – aufgerufen, daran anzuknüpfen. Dazu bietet sich die Regelungsform eines Rahmen- und Politikplanungsgesetzes an, wie sie schon aus dem Klimaschutzgesetz und dem Klimaanpassungsgesetz bekannt ist. Der Aufsatz beleuchtet den internationalen, europa- und verfassungsrechtlichen Hintergrund eines solchen ‘Biodiversitätsschutzgesetzes’ und diskutiert – unter Zusammenarbeit sowohl rechts- als auch naturwissenschaftlicher Autor:innen – formale und materielle Ausgestaltungsmöglichkeiten.

Description: A natural plankton community from oligotrophic subtropical waters of the Atlantic near Gran Canaria, Spain, was subjected to varying degrees of ocean alkalinity enhancement (OAE) to assess the potential physiological effects, in the context of the application of ocean carbon dioxide removal (CDR) techniques. We employed 8.3 m3 mesocosms with a sediment trap attached to the bottom, creating a gradient in total alkalinity (TA). The lowest point on this gradient was 2400 μmol · L-1, which corresponded to the natural alkalinity of the environment, and the highest point was 4800 μmol · L-1. Over the course of the 33-day experiment, the plankton community exhibited two distinct phases. In phase-I (days 5–20), a notable decline in the photosynthetic efficiency (Fv/Fm) was observed. This change was accompanied by substantial reductions in the abundances of picoeukaryotes, small size nanoeukaryotes (nanoeukaryotes-1), and microplankton. The cell viability of picoeukaryotes, as indicated by fluorescein-di-acetate hydrolysis by cellular esterases (FDA- green fluorescence), slightly increased by the end of phase-I whilst the viability of nanoeukaryotes 1 and Synechococcus spp . did not change. Reactive oxygen species levels (ROS-green fluorescence) showed no significant changes for any of the functional groups. In contrast, in phase-II (days 21–33), a pronounced community response was observed. Increases in Fv/Fm in the intermediate OAE treatments of ∆900 to ∆1800 μmol · L-1 and in chlorophyll-a (Chl-a), chlorophyll-c2 (Chl-c2) , fucoxanthin and divinyl-Chl-a were attributed to the emergence of blooms of large size nanoeukaryotes (nanoeukaryotes-2) from the genera Chrysochromulina, as well as picoeukaryotes. Synechococcus spp. also flourished towards the end of this phase. In parallel, we observed a total 20 % significant change in the metaproteome of the phytoplankton community. This is considered a significant alteration in protein expression, having substantial impacts on cellular functions and the physiology of the organisms. Medium levels of ∆TA showed more upregulated and less downregulated proteins than higher ∆TA treatments. Under these conditions, cell viability significantly increased in pico and nanoeukaryotes-1 in intermediate alkalinity levels, while in Synechococcus spp., nanoeukaryotes-2 and microplankton remained stable. ROS levels did not significantly change in any functional group. The pigment ratios DD+DT : FUCO, and DD+DT : Chl-a increased in medium ∆TA treatments, supporting the idea of nutrient deficiency alleviation and the absence of physiological stress. Taken all data together, this study shows that there is minimal evidence indicating a harmful impact of high alkalinity on the plankton community. The OAE treatments did not result in physiological fitness impairment, thus OAE did not cause cellular stress in the phytoplankton community studied.

Description: In the northeastern tropical Atlantic, a region of high potential vorticity (PV) determines the size of the exchange window for the interior thermocline flow of the subtropical cell via its variations in strength and extent. Variability of this PV barrier has the potential to impact the ventilation of the tropical Atlantic on decadal timescales. Here, the impact of the North Atlantic Oscillation (NAO) on the PV barrier related to isopycnals within the thermocline of the subtropical-tropical Atlantic Ocean is assessed from Argo observations for the time period of 2006-2022. Relative to the negative NAO phase (2009-2010), during the positive NAO phase (2014-2019), the North Atlantic subtropical high and the northeast trades are intensified. Satellite-derived wind stress curl shows increased upwelling/downwelling on the equatorward/poleward side of the trade wind zone, respectively. In the subtropical-tropical Atlantic, a symmetric pattern of isopycnal heave is observed: rising isopycnals within 20 degrees N and 20 degrees S and sinking poleward of that. With rising isopycnals, the PV barrier in the northeastern tropical Atlantic becomes stronger. Analyses of geostrophic velocities and the Sverdrup streamfunction show that during the positive NAO phase there are increased equatorward velocities at thermocline level along the western boundary and reduced velocities through the interior as a result of intensified northeast trades and therefore a strengthened PV barrier. Intensified trades lead to enhanced subduction of thermocline waters and, independent of that, to a strengthened Equatorial Undercurrent transport as observed at the mooring site at 0 degrees, 23 degrees W, likely via the pulling effect of the subtropical cells. In the North Atlantic Ocean, subducted water from the subtropics has two possible pathways within the thermocline toward the equatorial region: the interior pathway and the pathway along the western boundary. The size of the exchange window between subtropics and tropics depends on the extent of a barrier zone in the eastern part of the basin that is associated with wind-driven upwelling of density surfaces. The North Atlantic Oscillation (NAO) is the dominant atmospheric climate mode in the North Atlantic and in this study, we show how the NAO impacts the barrier for the equatorward thermocline flow in the tropical Atlantic Ocean. During positive NAO phases (e.g., 2014-2019), density surfaces become shallower and strengthen the barrier, while during negative NAO phases (e.g., 2009-2010) the barrier weakens. Geostrophic velocity analysis reveals that during positive NAO phases more thermocline water is transported equatorward via the western boundary and less via the interior pathway. Additionally, observations from a mooring site at 0 degrees, 23 degrees W show stronger Equatorial Undercurrent transport as a result of intensified trade winds during positive NAO phases. Trade winds in the northeastern tropical Atlantic strengthen during positive phases of the North Atlantic Oscillation (NAO+) Potential vorticity barrier for the interior equatorward thermocline flow of the North Atlantic Subtropical Cell strengthens during NAO+ Annual subduction of thermocline water and Equatorial Undercurrent transport increase simultaneously from 2008 to 2018

Description: Technologien für CO₂-Abscheidung und -Speicherung machen Hoffnung, werden aber gleichzeitig als Rechtfertigung für die geringe Reduktion von Emissionen aus fossilen Energiequellen genutzt. Das ist nicht vereinbar mit dem Ziel, die Erderwärmung auf 1,5 oder 2 °C zu begrenzen.