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  • 1
    Publication Date: 2021-04-25
    Keywords: 551 ; VKB 350 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 186-209
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  • 2
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    Springer | Berlin [u.a.]
    Publication Date: 2021-04-25
    Description: Colonial non-zooxanthellate corals from deep-water coral reefs, Lophelia pertusa and Madrepora oculata, produce large amounts of extracellular mucus (EMS). This mucus has various functions, e.g., an antifouling capability protecting the coral skeleton from attacks of endolithic and boring organisms. Both corals show thick epithecal and exothecal skeletal parts with a clear lamellar growth pattern. The formation of the epitheca is unclear. It is supposed that the EMS play a central role during the calcification process of the epithecal skeletal parts. Staining with the fluorochrome tetracycline has shown an enrichment of Ca2+ ions in the mucus. In order to investigate this hypothesis, the protein content of the mucus and the intracrystalline organic matter from newly formed epithecal aragonite of Madrepora oculata was determined via sodium dodecyl sulfate (SDS) gel electrophoresis. Identical band patterns within both substances could be detected, one around 45 kDa molecular weight and a cluster around 30-35 kDa molecular weight. The occurrence of identical protein patterns within the mucus and in the newly formed aragonite confirms the idea that the mucus plays an important role during the organomineralization of the coral epitheca.
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 731-744
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  • 3
    Publication Date: 2021-03-29
    Description: According to a model by Cerling (1991, 1999), the carbon isotope composition of calcretes should depend on the soil type and the CO2-concentration in the atmosphere. We have tested Cerling’s model by investigating 14 Palaeozoic sections with soil profiles. A large number of carbonate types of different genetic origin exist in the localities examined. Comparing the Palaeozoic samples with recent and subrecent calcretes, it can be demonstrated that anhedral, cryptocrystalline (〈10 μm) and subhedral microcrystalline (10 - 40 μm) carbonates are clearly of pedogenic origin. Crystals of larger size with a poikilotopic texture are of groundwater or burial diagenetic origin. Macro- and micromorphological features, typical of recent calcretes, occur in several soil profiles, but thin section microscopy reveals a strong diagenetic overprint of most pedogenic carbonates. Time equivalent sections with comparable soil types (protosols, calcisols and vertisols) show large variations in carbon isotope composition. On the other hand, different carbonate generations at one site do not differ much. Therefore Palaeozoic calcretes appear to be unsuitable for a deduction of the Palaeozoic CO2-concentration.
    Description: German Research Foundation (DFG)
    Description: research
    Keywords: 551.9 ; 552.5 ; VKB 350 ; VJJ 110 ; VCA 300 ; VKB 332 ; VKA 300 ; VKB 371 ; VEA 000 ; VKB 372 ; Lithogenese {Sedimentologie} ; Geochemie der Stabilen Isotopen ; Paläozoische Geologie ; Sedimentationsbedingungen ; Petrogenese ; Klastische Sedimentgesteine ; Europa insgesamt {Geologie} ; Karbonatische Sedimentgesteine ; Kohlenstoffkreislauf ; C-isotope ; Jungpaläozoikum ; Paläopedologie ; Kalkkruste ; CO2 ; calcrete ; carbon cycle ; upper Paleozoic ; paleosol ; C-13/C-12 ; Europa ; paläoklima ; Europe ; 38.41 ; 38.61 ; 38.32
    Language: English
    Type: article
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  • 4
    Publication Date: 2021-03-29
    Description: The incorporation of hydrogen in enstatite in a hydrous system containing various amounts of NaCl was investigated at 25 kbar. The hydrogen content in enstatite shows a clear negative correlation to the NaCl-concentration in the system. The most favourable explanation is the reduction of water fugacity due to dilution. Other reasons for the limited hydrogen incorporation at high NaCl levels, such as a significant influence of Na+ on the defect chemistry or an exchange between OH- and Cl-in enstatite, appear much less important. A partition coefficient D Na En/Fluid = 0.0013 could be determined, demonstrating that Na is less incompatible in enstatite than H. The new results support the idea that dissolved components have to be considered when the total hydrogen storage capacity in nominally anhydrous minerals is estimated, especially in geological settings with high levels of halogens, such as subduction zones.
    Keywords: KEnstatite; Hydrogen incorporation;Water activity; Sodium; Chlorine ; 551
    Language: English
    Type: article , publishedVersion
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  • 5
    Publication Date: 2021-03-29
    Description: The coprecipitation of U (VI) with iron corrosion products from aqueous solutions by zero valent iron was investigated. The evidence of coprecipitation was demonstrated by conducting experiments with well characterized scrap iron,pyrite and a mixture of both materials with experimental durations of up to four months. Results indicate that under anoxic conditions only less than one tenth of the immobilized U(VI) was associated with the surface of scrap iron, whereas theremaining amount is entrapped in aging corrosion products.
    Keywords: 551
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 577-586
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  • 6
    Publication Date: 2021-03-29
    Description: Five volcanic tuffs ranging from dacitic tuffs of Hungary to rhyolite, phonolite and basaltic tuffs of Germany were consolidated under laboratory conditions. Prior to consolidation an anti-hygro, a hydrous consolidant, which reduces the swelling ability of clay minerals, was applied. The three consolidants, a silicic acid ester (SAE), an elastic silicic acid ester (eSAE) and an acrylate resin (PMMA) were applied on test specimens under vacuum. Petrographic characterisation (polarizing microscopy, XRD, SEM) provided data for fabric analyses and the mineral composition of the tuffs. Changes in fabric, effective porosity, density, tensile strength, ultrasonic wave velocity were evaluated after the treatment. Weathering simulation tests such as hygric dilatation and thermal dilatation aimed to prove the effectiveness of consolidation and the durability of consolidated tuff samples. More than 500 samples were analysed. The tests showed that SAE caused the highest increase in indirect tensile strength. The water absorption and the pore size distribution of the tuffs were modified by consolidation. The PMMA reduced the water absorption the most, whereas SAE modified it the least. All the tested consolidants increased the thermal dilatation of the tuffs. The changes in hygric dilatation were not uniform: for most tuffs SAE increased and PMMA decreased the hygric dilatation, although the clay-rich Habichtswald tuff showed the opposite trend. The changes in hygric and thermal behaviour of consolidated tuff require special care when specific consolidants are chosen. These products modify the physical properties of consolidated tuffs and change the behaviour of weathering.
    Keywords: Strengthening agents; Tuff; Silicic acid ester; PMMA; Durability ; 551
    Language: English
    Type: article , publishedVersion
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  • 7
    Publication Date: 2021-03-29
    Keywords: Albrecht-von-Haller-Institut für Pflanzenwissenschaften / Abteilung für Palynologie und Klimadynamik ; Palaeolimnology; Holocene climate; Diatoms; Green algae; Pollen; Karst ; 551
    Language: English
    Type: article , publishedVersion
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  • 8
    Publication Date: 2021-03-29
    Description: A 782 d solubilization study using not shaken batch experiments and involving one uranium-bearing rock and three natural carbonate minerals was conducted to characterize uranium (U) leaching under oxic conditions. Results showed that aqueous U concentration increased continuously with a solubilization rate of 0.16 mgm-2h-1 for the first 564 d (1.5 y). After 1.5 y, U concentration reached a maximum value (saturation) and decreased afterwards. The saturation concentration of 54 mgL-1 (mean value) was influenced to various extent by the presence of carbonate minerals. Dissolution/precipitation, adsorption or ion exchange processes appear to control U solubilization.
    Keywords: 551
    Language: English
    Type: anthologyArticle , acceptedVersion
    Format: 425-435
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  • 9
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 179-211
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  • 10
    Publication Date: 2021-04-25
    Keywords: 551 ; VU 000 ; 38.20
    Language: English
    Type: anthologyArticle , publishedVersion
    Format: 102-120
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